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Valorization of AZ91 by the hydrolysis reaction for hydrogen production (Electrochemical approach)

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierLaboratoire de Chimie Physique des Matériaux [LCPM]
hal.structure.identifierPlateforme de Recherche en NanoSciences et NanoTechnologie [PR2N]
dc.contributor.authorAL BACHA, Serge
hal.structure.identifierInstitut de Mécanique et d'Ingénierie [I2M]
dc.contributor.authorAUBERT, Isabelle
hal.structure.identifierLaboratoire de Chimie Physique des Matériaux [LCPM]
hal.structure.identifierPlateforme de Recherche en NanoSciences et NanoTechnologie [PR2N]
dc.contributor.authorZAKHOUR, Mirvat
hal.structure.identifierLaboratoire de Chimie Physique des Matériaux [LCPM]
hal.structure.identifierPlateforme de Recherche en NanoSciences et NanoTechnologie [PR2N]
dc.contributor.authorNAKHL, Michel
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorBOBET, Jean-Louis
dc.date.issued2021-03
dc.identifier.issn2213-9567
dc.description.abstractEnThe hydrolysis of Mg-based materials appears to be an ideal solution for clean energy production. Green hydrogen was produced by the hydrolysis reaction of a "standard" AZ91 alloy (called AZ91 in the following) in "model" seawater solution. Two milling speeds (i.e. 250 rpm and 350 rpm) were tested to enhance the reactivity of AZ91. Graphite and AlCl 3 were used as ball milling additives. Milling at higher rotational speed is more energetic, hence it ameliorates the most the hydrolysis performance of AZ91. Comparing both milling additives, AlCl 3 enhances the most the hydrolysis of AZ91 with a generation of 65% of its theoretical H 2 generation capacity. The best material was obtained by milling AZ91 at 350 rpm with graphite for 2 h followed by a further milling with AlCl 3 for 2 h-a yield of 75% of its theoretical H 2 generation capacity was reached within a few minutes. The corrosion behavior of milled AZ91 was investigated by anodic polarization and electrochemical impedance spectroscopy (EIS). The calculated electrochemical parameters from EIS fitting of two materials milled under different conditions but with the same milling additive are approximately the same. This suggests that, in order to fully evaluate the reactivity of AZ91, hydrolysis, anodic polarization and EIS must be considered.
dc.language.isoen
dc.publisherElsevier
dc.subject.enBall milling
dc.subject.enAZ91
dc.subject.enMg17Al12
dc.subject.enCorrosion
dc.subject.enHydrogen
dc.subject.enElectrochemical impedance spectroscopy
dc.title.enValorization of AZ91 by the hydrolysis reaction for hydrogen production (Electrochemical approach)
dc.typeArticle de revue
dc.identifier.doi10.1016/j.jma.2020.12.007
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Magnesium and Alloys
bordeaux.page1942-1953
bordeaux.volume9
bordeaux.issue6
bordeaux.peerReviewedoui
hal.identifierhal-03467751
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-03467751v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Magnesium%20and%20Alloys&rft.date=2021-03&rft.volume=9&rft.issue=6&rft.spage=1942-1953&rft.epage=1942-1953&rft.eissn=2213-9567&rft.issn=2213-9567&rft.au=AL%20BACHA,%20Serge&AUBERT,%20Isabelle&ZAKHOUR,%20Mirvat&NAKHL,%20Michel&BOBET,%20Jean-Louis&rft.genre=article


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