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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPOUCHARD, Michel
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDOUMERC, Jean-Pierre
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorVILLESUZANNE, Antoine
dc.date.issued2008
dc.identifier.issn0020-1669
dc.description.abstractEnWhile approaching a Mott−Hubbard transition by hole doping of the pristine La2CuO4 cuprate, excitons are created because of exciton−exciton and exciton-doping hole stabilizing interactions. Here, excitons are of charge-transfer Frenkel-type, with effective Cu+O− electrical dipoles that solvate the doping charges. Assuming a moderate screening by charge carriers, we show that mobile exciton-solvated doping holes should be associated in pairs either by a deep energy well or as thermodynamically stable pairs that can glide in the [100] or [010] direction after Bose condensation. Exciton−exciton dipolar interactions constitute thus the “pairing glue” in this model, which is based on instantaneous interactions and intrinsically differs from the previous excitonic models, in which BCS virtual phonons were replaced by virtual excitons.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.subject.enCharge transfer
dc.subject.enCuprates
dc.subject.enHigh-Tc
dc.subject.enExcitons
dc.title.enReal-space pairing through charge transfer excitons in High-Tc cuprates
dc.typeArticle de revue
dc.identifier.doi10.1021/ic801266q
dc.subject.halChimie/Matériaux
bordeaux.journalInorganic Chemistry
bordeaux.page11958-11964
bordeaux.volume47
bordeaux.issue24
bordeaux.peerReviewedoui
hal.identifierhal-00350956
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00350956v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Inorganic%20Chemistry&rft.date=2008&rft.volume=47&rft.issue=24&rft.spage=11958-11964&rft.epage=11958-11964&rft.eissn=0020-1669&rft.issn=0020-1669&rft.au=POUCHARD,%20Michel&DOUMERC,%20Jean-Pierre&VILLESUZANNE,%20Antoine&rft.genre=article


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