Reactivity at the electrode-electrolyte interfaces in Li-ion and gel electrolyte lithium batteries for LiNi0.6Mn0.2Co0.2O2 with different particle sizes
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | SOLOY, Adrien | |
hal.structure.identifier | Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux [IPREM] | |
hal.structure.identifier | Réseau sur le stockage électrochimique de l'énergie [RS2E] | |
dc.contributor.author | FLAHAUT, Delphine | |
hal.structure.identifier | Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux [IPREM] | |
hal.structure.identifier | Réseau sur le stockage électrochimique de l'énergie [RS2E] | |
dc.contributor.author | FOIX, Dominique | |
hal.structure.identifier | Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux [IPREM] | |
hal.structure.identifier | Réseau sur le stockage électrochimique de l'énergie [RS2E] | |
dc.contributor.author | ALLOUCHE, Joachim | |
hal.structure.identifier | Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux [IPREM] | |
hal.structure.identifier | Réseau sur le stockage électrochimique de l'énergie [RS2E] | |
dc.contributor.author | VALLVERDU, Germain | |
hal.structure.identifier | SAFT [Bordeaux] | |
dc.contributor.author | DUMONT, Erwan | |
hal.structure.identifier | SAFT [Bordeaux] | |
dc.contributor.author | GAL, Lucille | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
hal.structure.identifier | Advanced Lithium Energy Storage Systems - ALISTORE-ERI [ALISTORE-ERI] | |
hal.structure.identifier | Réseau sur le stockage électrochimique de l'énergie [RS2E] | |
dc.contributor.author | WEILL, François | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
hal.structure.identifier | Advanced Lithium Energy Storage Systems - ALISTORE-ERI [ALISTORE-ERI] | |
hal.structure.identifier | Réseau sur le stockage électrochimique de l'énergie [RS2E] | |
dc.contributor.author | CROGUENNEC, Laurence | |
dc.date.issued | 2022 | |
dc.identifier.issn | 1944-8244 | |
dc.description.abstractEn | The layered oxide LiNi0.6Mn0.2Co0.2O2 is a very attractive positive electrode material, as shown by good reversible capacity, chemical stability and cyclability upon long range cycling in Li-ion batteries and, hopefully, in a near future, in all-solid-state batteries. Three samples with variable primary particle sizes of 240 nm, 810 nm and 2.1 µm in average and very similar structures close to the ideal 2D layered structure (less than 2% Ni2+ ions in Li+ sites) were obtained by coprecipitation followed by solid-state reaction at high temperature. The electrochemical performances of the materials were evaluated in a conventional organic liquid electrolyte in Li-ion batteries and in a gel electrolyte in all-solid-state batteries. The positive electrode/electrolyte interface was analysed by X-Ray photoelectron spectroscopy in order to determine its composition and the extent of the degradation of the lithium salt and the carbonate solvents after cycling, taking into account the changes in particle size of the positive electrode material and the nature of the electrolyte. | |
dc.description.sponsorship | Laboratory of excellency for electrochemical energy storage - ANR-10-LABX-0076 | |
dc.language.iso | en | |
dc.publisher | Washington, D.C. : American Chemical Society | |
dc.subject.en | Li-ion battery | |
dc.subject.en | All-Solid-State batteries | |
dc.subject.en | Layered oxide | |
dc.subject.en | NMC | |
dc.subject.en | Reactivity | |
dc.subject.en | Gelified electrolyte Morphology | |
dc.title.en | Reactivity at the electrode-electrolyte interfaces in Li-ion and gel electrolyte lithium batteries for LiNi0.6Mn0.2Co0.2O2 with different particle sizes | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1021/acsami.2c04249 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | ACS Applied Materials & Interfaces | |
bordeaux.page | 5617–5632. | |
bordeaux.volume | 5 | |
bordeaux.issue | 5 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-03684124 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-03684124v1 | |
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