Ferromagnetic Ordering in CeZnSn
| hal.structure.identifier | Institut für Anorganische und Analytische Chemie | |
| dc.contributor.author | HERMES, Wilfried | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MATAR, Samir F. | |
| hal.structure.identifier | Institut für Anorganische und Analytische Chemie | |
| dc.contributor.author | HARMENING, Thomas | |
| hal.structure.identifier | Institut für Anorganische und Analytische Chemie | |
| dc.contributor.author | RODEWALD, Ute Ch. | |
| hal.structure.identifier | Institut für Anorganische und Analytische Chemie | |
| dc.contributor.author | EUL, Matthias | |
| hal.structure.identifier | Institut für Anorganische und Analytische Chemie | |
| dc.contributor.author | PÖTTGEN, Rainer | |
| dc.date.issued | 2009 | |
| dc.identifier.issn | 0932-0776 | |
| dc.description.abstractEn | The stannide CeZnSn was obtained in X-ray-pure form by induction-melting of the elements in a sealed tantalum ampoule. CeZnSn crystallizes with the YPtAs-type structure, space groupP63/mmc,a= 456.7(3),c= 1673.8(5) pm,wR2 = 0.0862, 259F2values, and 12 variables. The zinc and tin atoms build up puckered Zn3Sn3hexagons (Zn–Sn 271 pm) with weak interlayer Zn–Zn interactions(323 pm). Susceptibility measurements of CeZnSn reveal modified Curie-Weiss behavior above 50 Kwith an experimental magnetic moment of 2.77(1)μB/ Ce atom. The cerium magnetic moments order ferromagnetically atTC=5.2(1)K.119Sn Mössbauer spectra show a single tin site at an isomer shift ofδ= 1.967(4) mm/s subjected to a small quadrupole splitting of ∆EQ= 0.41(2) mm/s at 40 K. At 4.2 K a magnetic hyperfine field of 0.872(5) T is transferred to the tin site. From DFT scalar relativistic calculations of the electronic and magnetic structures, chemical bonding analysis reveals on one hand a weaker bonding of Zn than of Sn with the cerium substructures with a twice strongerCe1–Sn bond compared to Ce2–Sn. On the other hand, a ferromagnetic ground state is identified from total energy differences in agreement with experiment | |
| dc.language.iso | en | |
| dc.publisher | Verlag der Zeitschrift Fuer Naturforschung | |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/ | |
| dc.subject.en | Intermetallics | |
| dc.subject.en | Stannide | |
| dc.subject.en | Crystal Chemistry | |
| dc.subject.en | Chemical Bonding (COOP) | |
| dc.subject.en | DFT | |
| dc.subject.en | Spin Polarized Calculations | |
| dc.subject.en | DOS | |
| dc.subject.en | ELF | |
| dc.title.en | Ferromagnetic Ordering in CeZnSn | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1515/znb-2009-0206 | |
| dc.subject.hal | Chimie/Matériaux | |
| dc.subject.hal | Chimie/Cristallographie | |
| dc.subject.hal | Chimie/Chimie inorganique | |
| bordeaux.journal | Zeitschrift fur Naturforschung B | |
| bordeaux.page | 175-183 | |
| bordeaux.volume | 64 | |
| bordeaux.issue | 2 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00362491 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00362491v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Zeitschrift%20fur%20Naturforschung%20B&rft.date=2009&rft.volume=64&rft.issue=2&rft.spage=175-183&rft.epage=175-183&rft.eissn=0932-0776&rft.issn=0932-0776&rft.au=HERMES,%20Wilfried&MATAR,%20Samir%20F.&HARMENING,%20Thomas&RODEWALD,%20Ute%20Ch.&EUL,%20Matthias&rft.genre=article |
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