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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierAdvanced Lithium Energy Storage Systems - ALISTORE-ERI [ALISTORE-ERI]
hal.structure.identifierRéseau sur le stockage électrochimique de l'énergie [RS2E]
dc.contributor.authorOLCHOWKA, Jacob
hal.structure.identifierLaboratoire de Chimie de la Matière Condensée de Paris [LCMCP]
hal.structure.identifierRéseau sur le stockage électrochimique de l'énergie [RS2E]
dc.contributor.authorFANG, Runhe
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorBIANCHINI NUERNBERG, Rafael
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierLaboratoire réactivité et chimie des solides - UMR CNRS 7314 UPJV [LRCS]
hal.structure.identifierRéseau sur le stockage électrochimique de l'énergie [RS2E]
dc.contributor.authorPABLOS, Chloé
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierAdvanced Lithium Energy Storage Systems - ALISTORE-ERI [ALISTORE-ERI]
dc.contributor.authorCARLIER, Dany
hal.structure.identifierLaboratoire de Chimie de la Matière Condensée de Paris [LCMCP]
hal.structure.identifierRéseau sur le stockage électrochimique de l'énergie [RS2E]
dc.contributor.authorCASSAIGNON, Sophie
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierAdvanced Lithium Energy Storage Systems - ALISTORE-ERI [ALISTORE-ERI]
hal.structure.identifierRéseau sur le stockage électrochimique de l'énergie [RS2E]
dc.contributor.authorCROGUENNEC, Laurence
dc.date.issued2022
dc.identifier.issn2040-3364
dc.description.abstractEnNa(3)V(2)(PO(4))(2)FO(2) is a promising candidate for practical use as a positive electrode material in Na-ion batteries thanks to its high voltage and excellent structural stability upon cycling. However, its limited intrinsic transport properties limit its performance at fast charge/discharge rates. In this work, two efficient approaches are presented to optimize the electrical conductivity of the electrode material: particle nanosizing and particle coating with an ionic liquid (IL). The former reveals that particle downsizing from micrometer to nanometer range improves the electronic conductivity by more than two orders of magnitude, which greatly improves the rate capability without affecting the capacity retention. The second approch dealing with an original surface modification by applying an IL coating strongly enhances the ionic mobility and offers new perspectives to improve the energy storage performance by designing the electrode materials' surface composition.
dc.description.sponsorshipLaboratory of excellency for electrochemical energy storage - ANR-10-LABX-0076
dc.description.sponsorshipDes liquides ioniques pour nano-structurer et fonctionnaliser la surface de matériaux d'électrode - ANR-21-CE50-0006
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.title.enParticle Nanosizing and Coating with an Ionic Liquid: Two Routes to Improve the Transport Properties of Na(3)V(2)(PO(4))(2)FO(2).
dc.typeArticle de revue
dc.identifier.doi10.1039/d2nr01080a
dc.subject.halChimie/Matériaux
dc.subject.halChimie/Chimie inorganique
bordeaux.journalNanoscale
bordeaux.page8663-8676
bordeaux.volume14
bordeaux.issue24
bordeaux.peerReviewedoui
hal.identifierhal-03692962
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-03692962v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Nanoscale&rft.date=2022&rft.volume=14&rft.issue=24&rft.spage=8663-8676&rft.epage=8663-8676&rft.eissn=2040-3364&rft.issn=2040-3364&rft.au=OLCHOWKA,%20Jacob&FANG,%20Runhe&BIANCHINI%20NUERNBERG,%20Rafael&PABLOS,%20Chlo%C3%A9&CARLIER,%20Dany&rft.genre=article


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