NdNiMg5, a New Magnesium-Rich Phase with an Unusual Structural Type.
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| hal.structure.identifier | Département de Chimie | |
| dc.contributor.author | OURANE, Bassem | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GAUDIN, Etienne | |
| hal.structure.identifier | Département de Chimie | |
| dc.contributor.author | ZOUARI, Ridha | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | COUILLAUD, Samuel | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | BOBET, Jean-Louis | |
| dc.date.issued | 2013 | |
| dc.identifier.issn | 0020-1669 | |
| dc.description.abstractEn | The new intermetallic NdNiMg5 was discovered during the study of the Mg-rich part of the Mg-Nd-Ni system. It was synthetized by melting of the constituent elements in a sealed tantalum tube with subsequent annealing. Its structure was determined by X-ray diffraction on a single crystal. Crystal data: orthorhombic system, Cmcm, Z = 4, a = 4.4799(2) Å, b = 9.9827(3) Å, c = 13.7854(10) Å, dcalc = 3.49 g*cm(-3). Its structure is made of infinite layers of Mg atoms that form blocks stacked along the c axis. These blocks, with a close-packed array of Mg atoms, are separated by infinite NiNd layers and connected through short Mg-Mg bonds. In the NiNd layer, the Ni and Nd atoms form an ordered graphite-type network. Antiferromagnetic ordering is observed with TN = 12 K, and the effective magnetic moment μeff is equal to 3.89(1) μB. | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.subject.en | Intermetallics | |
| dc.subject.en | Inorganic compounds | |
| dc.subject.en | Crystallography | |
| dc.title.en | NdNiMg5, a New Magnesium-Rich Phase with an Unusual Structural Type. | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/ic401911g | |
| dc.subject.hal | Chimie/Matériaux | |
| dc.subject.hal | Chimie/Chimie inorganique | |
| bordeaux.journal | Inorganic Chemistry | |
| bordeaux.page | 13289-13291 | |
| bordeaux.volume | 52 | |
| bordeaux.issue | 23 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00913633 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00913633v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Inorganic%20Chemistry&rft.date=2013&rft.volume=52&rft.issue=23&rft.spage=13289-13291&rft.epage=13289-13291&rft.eissn=0020-1669&rft.issn=0020-1669&rft.au=OURANE,%20Bassem&GAUDIN,%20Etienne&ZOUARI,%20Ridha&COUILLAUD,%20Samuel&BOBET,%20Jean-Louis&rft.genre=article |
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