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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCOUILLAUD, Samuel
hal.structure.identifierNational Institute of Advanced Industrial Science and Technology [AIST]
dc.contributor.authorENOKI, H.
hal.structure.identifierPhysics Department, Institut de Recherche sur l'Hydroge?ne
dc.contributor.authorAMIRA, S.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorBOBET, Jean-Louis
hal.structure.identifierNational Institute of Advanced Industrial Science and Technology [AIST]
dc.contributor.authorAKIBA, Etsuo
hal.structure.identifierPhysics Department, Institut de Recherche sur l'Hydroge?ne
dc.contributor.authorHUOT, J.
dc.date.issued2009
dc.identifier.issn0925-8388
dc.description.abstractEnThe effect of high energy milling and cold rolling on the BCC solid solution TiV<sub>1.6</sub>Mn<sub>0.4</sub> was investigated. The as-cast alloy presented a nanocrystalline structure with a crystallite size of 17 nm. After 5 h of milling a slight reduction of crystallite size was measured and the BCC solid solution lattice parameter was reduced from 3.082 Å to 3.061 Å. Cold rolling also had for effect a reduction of crystallite size and lattice parameter. The main effect of cold rolling was to produce a highly textured alloy along the (2 0 0) Bragg peak. The as-cast alloy could store a maximum of 3.48 wt.% of hydrogen at 423 K and has a reversible capacity of 1.8 wt.%. The ball -milled and cold rolled samples did not absorb hydrogen even after 10 hydrogenation/dehydrogenation cycles. Possible reasons why ball milled and cold rolled samples did not absorb hydrogen are discussed.
dc.language.isoen
dc.publisherElsevier
dc.subject.enCold rolling
dc.subject.enBall milling
dc.subject.enBCC alloys
dc.subject.enNanocrystalline
dc.subject.enHydrogen absorption
dc.title.enEffect of ball milling and cold rolling on hydrogen storage properties of nanocrystalline TiV<sub>1.6</sub>Mn<sub>0.4</sub> alloy
dc.typeArticle de revue
dc.identifier.doi10.1016/j.jallcom.2009.05.037
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Alloys and Compounds
bordeaux.page154-158
bordeaux.volume484
bordeaux.issue1-2
bordeaux.peerReviewedoui
hal.identifierhal-00426236
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00426236v1
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