New photomagnetic cyanido-bridged Cu(II)-Mo(IV) oligonuclear complexes: slight modification of the blocking ligands induces different structures
| hal.structure.identifier | Inorganic Chemistry Laboratory-Faculty of Chemistry | |
| dc.contributor.author | MAXIM, Catalin | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MATHONIÈRE, Corine | |
| hal.structure.identifier | Inorganic Chemistry Laboratory-Faculty of Chemistry | |
| dc.contributor.author | ANDRUH, Marius | |
| dc.date.issued | 2009 | |
| dc.identifier.issn | 1477-9226 | |
| dc.description.abstractEn | A pentanuclear complex, [Mo(CN)8{CuL1}2{CuL1(H2O)}2].6H2O 1, and a decanuclear one, [Mo(CN)8{CuL2}3{CuL2(H2O)}]2.10H2O 2, have been obtained following the building-block approach (HL1 and HL2 are tridentate Schiff bases obtained by reacting salicylaldehyde with 2-aminomethyl-pyridine and 2-aminoethyl-pyridine, respectively). Both compounds present reversible photo-induced magnetic properties interpreted as a MoIV-CuII charge transfer. Compound 2 exhibits a lower efficiency of this metal-metal charge transfer than compound 1 attributed to a less flexible structure of 2 compared to 1. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | |
| dc.title.en | New photomagnetic cyanido-bridged Cu(II)-Mo(IV) oligonuclear complexes: slight modification of the blocking ligands induces different structures | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/b905621a | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Dalton Transactions | |
| bordeaux.page | 7805-7810 | |
| bordeaux.issue | 37 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00432943 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00432943v1 | |
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