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Two new 1-D dicyanamide bridged polymeric complexes [Mn(μ1,5-dca)2(salicyh)2]n and {[Ni(μ1,5-dca)(TTA)](ClO4)}n (dca = dicyanamide, ; salicyh = salicylic hydrazide; TTA = triethylenetetramine): Synthesis, structures and magnetic studies

hal.structure.identifierDepartment of Chemistry
dc.contributor.authorSEN, Soma
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorPRITHA, Talukder
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorSAMIRAN, Mitra
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorGEORGINA, Rosair
hal.structure.identifierDepartment of Chemistry and Biochemistry [Newak]
dc.contributor.authorYAP, Glenn
hal.structure.identifierLaboratoire für Kristallographie
dc.contributor.authorVOLKER, Gramlich
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorKIM, Jinkwon
hal.structure.identifierDepartment of Materials Chemistry
dc.contributor.authorMATSUSHITA, T.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDESPLANCHES, Cédric
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierLaboratoire de chimie de coordination [LCC]
dc.contributor.authorSUTTER, Jean-Pascal
dc.date.created2005
dc.date.issued2005
dc.identifier.issn0020-1693
dc.description.abstractEnTwo new dicyanamide bridged complexes [Mn(μ1,5-dca)2(salicyh)2]n (1) and {[Ni(μ1,5-dca)(TTA)](ClO4)}n (2) (dca = dicyanamide, ; salicyh = salicylic hydrazide; TTA = triethylenetetramine) have been synthesised and structurally characterised. Both the compounds 1 and 2 consist in 1-D coordination polymers. In 1 the manganese atoms are doubly bridged by μ1,5-dca ligands, whereas in 2 the nickel atoms are bridged by a single μ1,5-dca ligand. The magnetic measurements indicate that whereas intrachain interactions take place between the metal ions for compound 1 (J = −0.26 cm−1), no evidence for any exchange coupling is found for compound 2
dc.language.isoen
dc.publisherElsevier
dc.title.enTwo new 1-D dicyanamide bridged polymeric complexes [Mn(μ1,5-dca)2(salicyh)2]n and {[Ni(μ1,5-dca)(TTA)](ClO4)}n (dca = dicyanamide, ; salicyh = salicylic hydrazide; TTA = triethylenetetramine): Synthesis, structures and magnetic studies
dc.typeArticle de revue
dc.identifier.doi10.1016/j.ica.2005.08.006
dc.subject.halChimie/Matériaux
bordeaux.journalInorganica Chimica Acta
bordeaux.pagep. 4534-4540
bordeaux.volumevol. 358, n°15
bordeaux.peerReviewedoui
hal.identifierhal-00015150
hal.version1
hal.popularnon
hal.audienceNon spécifiée
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00015150v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Inorganica%20Chimica%20Acta&rft.date=2005&rft.volume=vol.%20358,%20n%C2%B015&rft.spage=p.%204534-4540&rft.epage=p.%204534-4540&rft.eissn=0020-1693&rft.issn=0020-1693&rft.au=SEN,%20Soma&PRITHA,%20Talukder&SAMIRAN,%20Mitra&GEORGINA,%20Rosair&YAP,%20Glenn&rft.genre=article


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