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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorSIMON, Annie
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorRAVEZ, Jean
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMAGLIONE, Mario
dc.date.created2005
dc.date.issued2005
dc.identifier.issn1293-2558
dc.description.abstractEnStarting from the well-known ferroelectric material BaTiO3, we show that coupled substitutions at the Ba and Ti cationic sites are able to improve the material properties. The compositions Ba0.9Bi0.067(Ti1−xZrx)O3 display a relaxor behaviour close to room temperature which open the way for possible use of it for capacitor applications. The origin of such optimization is related to the Bi cations which share similar electronic structure with Pb without raising environmental concerns related to the volatility of PbO. In addition, we have found a very peculiar transition sequence in this compound from paraelectric to ferroelectric and then to relaxor on cooling.
dc.language.isoen
dc.publisherElsevier
dc.subject.enFerroelectric
dc.subject.enRelaxor
dc.subject.enPerovskite
dc.title.enRelaxor properties of Ba0.9Bi0.067(Ti1−xZrx)O3 ceramics
dc.typeArticle de revue
dc.identifier.doi10.1016/j.solidstatesciences.2005.04.009
dc.subject.halChimie/Matériaux
bordeaux.journalSolid State Sciences
bordeaux.pagep. 925-930
bordeaux.volumevol. 7, n° 8
bordeaux.peerReviewedoui
hal.identifierhal-00015537
hal.version1
hal.popularnon
hal.audienceNon spécifiée
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00015537v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Solid%20State%20Sciences&rft.date=2005&rft.volume=vol.%207,%20n%C2%B0%208&rft.spage=p.%20925-930&rft.epage=p.%20925-930&rft.eissn=1293-2558&rft.issn=1293-2558&rft.au=SIMON,%20Annie&RAVEZ,%20Jean&MAGLIONE,%20Mario&rft.genre=article


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