Mostrar el registro sencillo del ítem

Mechanochromic and thermochromic luminescence of a copper iodide cluster

hal.structure.identifierLaboratoire de physique de la matière condensée [LPMC]
dc.contributor.authorPERRUCHAS, Sandrine
hal.structure.identifierLaboratoire Hétéroéléments et Coordination [DCPH]
dc.contributor.authorLE GOFF, X.
hal.structure.identifierLaboratoire Hétéroéléments et Coordination [DCPH]
dc.contributor.authorMARON, Sébastien
hal.structure.identifierLaboratoire de physique de la matière condensée [LPMC]
dc.contributor.authorMAURIN, Isabelle
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUILLEN, François
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGARCIA, Alain
hal.structure.identifierLaboratoire de physique de la matière condensée [LPMC]
dc.contributor.authorGACOIN, Thierry
hal.structure.identifierLaboratoire de physique de la matière condensée [LPMC]
dc.contributor.authorBOILOT, Jean-Pierre
dc.date.issued2010
dc.identifier.issn0002-7863
dc.description.abstractEnThe mechanochromic and thermochromic luminescence properties of a molecular copper(I) iodide cluster formulated [Cu<sub>4</sub>I<sub>4</sub>(PPh<sub>2</sub>(CH<sub>2</sub>CH═CH<sub>2</sub>))<sub>4</sub>] are reported. Upon mechanical grinding in a mortar, its solid-state emission properties are drastically modified as well as its thermochromic behavior. This reversible phenomenon has been attributed to distortions in the crystal packing leading to modifications of the intermolecular interactions and thus of the [Cu<sub>4</sub>I<sub>4</sub>] cluster core geometry. Notably, modification of the Cu−Cu interactions seems to be involved in this phenomenon directly affecting the emissive properties of the cluster.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.title.enMechanochromic and thermochromic luminescence of a copper iodide cluster
dc.typeArticle de revue
dc.identifier.doi10.1021/ja103431d
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of the American Chemical Society
bordeaux.page10967-10969
bordeaux.volume132
bordeaux.issue32
bordeaux.peerReviewedoui
hal.identifierhal-00528036
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00528036v1
bordeaux.COinSctx_ver=Z39.88-2004&amp;rft_val_fmt=info:ofi/fmt:kev:mtx:journal&amp;rft.jtitle=Journal%20of%20the%20American%20Chemical%20Society&amp;rft.date=2010&amp;rft.volume=132&amp;rft.issue=32&amp;rft.spage=10967-10969&amp;rft.epage=10967-10969&amp;rft.eissn=0002-7863&amp;rft.issn=0002-7863&amp;rft.au=PERRUCHAS,%20Sandrine&amp;LE%20GOFF,%20X.&amp;MARON,%20S%C3%A9bastien&amp;MAURIN,%20Isabelle&amp;GUILLEN,%20Fran%C3%A7ois&amp;rft.genre=article


Archivos en el ítem

ArchivosTamañoFormatoVer

No hay archivos asociados a este ítem.

Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem