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Synthesis, structure, magnetic, optical and Mössbauer properties of Na2FeSn(PO4)3

hal.structure.identifierLaboratoire de Chimie des Matériaux Solides
dc.contributor.authorEL BOUARI, A.
hal.structure.identifierLaboratoire de Chimie des Matériaux Solides
dc.contributor.authorEL JAZOULI, Abdelaziz
hal.structure.identifierLaboratoire de Chimie des Matériaux Solides
dc.contributor.authorBENMOKHTAR, Said
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGRAVEREAU, Pierre
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorWATTIAUX, Alain
dc.date.issued2010
dc.identifier.issn0925-8388
dc.description.abstractEnThe phosphate Na2FeSn(PO4)3, obtained by solid state reaction, was found to be isotypic with Na2CrTi(PO4)3, with space group R-3c and unit cell parameters a = 8.6617(2)Å, c=22.0161(7)A, V = 1430.47(5)Å3, Z=6. The structural parameters refined using Rietveld method showed that the Na+ ions occupy totally the M1 sites and partially the M2 sites and sharing faces with the [Sn/FeO6] octahedra. The presence of the unique valence of ferric iron in the reported phosphate was confirmed using UV-visible diffuse-reflectance spectroscopy, magnetic measurements and Mössbauer spectroscopy.
dc.language.isoen
dc.publisherElsevier
dc.subject.enNasicon-phosphates
dc.subject.enRietveld
dc.subject.enNa2FeSn(PO4)3
dc.subject.enMagnetic measurements
dc.subject.enUV–visible
dc.subject.enMössbauer spectroscopy
dc.title.enSynthesis, structure, magnetic, optical and Mössbauer properties of Na2FeSn(PO4)3
dc.typeArticle de revue
dc.identifier.doi10.1016/j.jallcom.2010.05.037
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Alloys and Compounds
bordeaux.page480-484
bordeaux.volume503
bordeaux.issue2
bordeaux.peerReviewedoui
hal.identifierhal-00529849
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00529849v1
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