High performance praseodymium nickelate oxide cathode for low temperature solid oxide fuel cell
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | FERCHAUD, Claire | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GRENIER, Jean-Claude | |
| hal.structure.identifier | Energy Research Centre of the Netherlands [ECN] | |
| dc.contributor.author | ZHANG-STEENWINKEL, Ye | |
| hal.structure.identifier | Energy Research Centre of the Netherlands [ECN] | |
| dc.contributor.author | VAN TUEL, Marc M. A. | |
| hal.structure.identifier | Energy Research Centre of the Netherlands [ECN] | |
| dc.contributor.author | VAN BERKEL, Frans P. F. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | BASSAT, Jean-Marc. | |
| dc.date.issued | 2011 | |
| dc.identifier.issn | 0378-7753 | |
| dc.description.abstractEn | The praseodymium nickelate oxide Pr<sub>2</sub>NiO<sub>4+<i>δ</i></sub>, a mixed conducting oxide with the K<sub>2</sub>NiF<sub>4</sub>-type structure, was evaluated as cathode for low temperature solid oxide fuel cells (<i>T</i> = 873 K). The electrochemical performance of the cathode has been improved by optimization of the microstructure of the porous cathode combined with the use of a ceria barrier layer in between the cathode and zirconia electrolyte. Both low polarization and ohmic resistances were obtained using Pr<sub>2</sub>NiO<sub>4+<i>δ</i></sub>-powders with a median particle size of 0.4 μm, and sintering the screen printed layer at a sintering temperature of about 1353 K for 1 h. These manufacturing conditions resulted in a cathode microstructure with well established connections between the cathode particles and good adhesion of the cathode on the electrolyte. Full-sized anode supported cells have been manufactured using the same process conditions for the Pr<sub>2</sub>NiO<sub>4+<i>δ</i></sub> cathode and tested. The best results were obtained when using a dense Ce<sub>0.8</sub>Gd<sub>0.2</sub>O<sub>1.9</sub> (20CGO) barrier layer. While a complete optimization of the cell preparation has not yet been achieved, the electrochemical performances of anode supported cells with Pr<sub>2</sub>NiO<sub>4+<i>δ</i></sub> are higher than those with the well known state-of-the-art La<sub>0.6</sub>Sr<sub>0.4</sub>Fe<sub>0.8</sub>Co<sub>0.2</sub>O<sub>3−<i>δ</i></sub> (LSFC) material. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.title.en | High performance praseodymium nickelate oxide cathode for low temperature solid oxide fuel cell | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.jpowsour.2010.09.036 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Journal of Power Sources | |
| bordeaux.page | 1872-1879 | |
| bordeaux.volume | 196 | |
| bordeaux.issue | 4 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00551672 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| dc.subject.es | Solid oxide fuel cell (SOFC) | |
| dc.subject.es | Cathode | |
| dc.subject.es | Praseodymium nickelate oxide | |
| dc.subject.es | Impedance spectroscopy | |
| dc.subject.es | Cell performance test | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00551672v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Power%20Sources&rft.date=2011&rft.volume=196&rft.issue=4&rft.spage=1872-1879&rft.epage=1872-1879&rft.eissn=0378-7753&rft.issn=0378-7753&rft.au=FERCHAUD,%20Claire&GRENIER,%20Jean-Claude&ZHANG-STEENWINKEL,%20Ye&VAN%20TUEL,%20Marc%20M.%20A.&VAN%20BERKEL,%20Frans%20P.%20F.&rft.genre=article |
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