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(Li/Ag)CoO(2): A New Intergrowth Cobalt Oxide Composed of Rock Salt and Delafossite Layers.

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorBERTHELOT, Romain
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPOLLET, Michaël
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDOUMERC, Jean-Pierre
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDELMAS, Claude
dc.date.issued2011
dc.identifier.issn0020-1669
dc.description.abstractEnA new ordered (Li/Ag)CoO(2) layered compound with an unusual oxygen packing combining rock salt and delafossite layers is obtained during the (Li(+), Na(+))/Ag(+) ionic exchange from the OP4-(Li/Na)CoO(2) precursor. This compound is actually an intermediate step to the final D4-AgCoO(2) delafossite and can be isolated thanks to the kinetics difference between the Li(+)/Ag(+) and Na(+)/Ag(+) exchange processes. It crystallizes in the P6(3)/mmc space group with cell parameters a(hex.) = 2.848(3) Å and c(hex.) = 21.607(7) Å. The details of the structure as well as its thermal stability and transport properties are presented and discussed.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.title.en(Li/Ag)CoO(2): A New Intergrowth Cobalt Oxide Composed of Rock Salt and Delafossite Layers.
dc.typeArticle de revue
dc.identifier.doi10.1021/ic200534x
dc.subject.halChimie/Matériaux
bordeaux.journalInorganic Chemistry
bordeaux.page6649-6655
bordeaux.volume50
bordeaux.issue14
bordeaux.peerReviewedoui
hal.identifierhal-00607966
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00607966v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Inorganic%20Chemistry&rft.date=2011&rft.volume=50&rft.issue=14&rft.spage=6649-6655&rft.epage=6649-6655&rft.eissn=0020-1669&rft.issn=0020-1669&rft.au=BERTHELOT,%20Romain&POLLET,%20Micha%C3%ABl&DOUMERC,%20Jean-Pierre&DELMAS,%20Claude&rft.genre=article


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