Luminescent properties of Eu3+-doped yttrium or gadolinium phosphates.
hal.structure.identifier | Center of Analytical Services and Experimentation, Department of Industry | |
dc.contributor.author | TUAN, D. C. | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | OLAZCUAGA, Roger | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | GUILLEN, François | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | GARCIA, Alain | |
hal.structure.identifier | Laboratoire de Physico-Chimie des Matériaux Luminescents [LPCML] | |
dc.contributor.author | MOINE, B. | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | FOUASSIER, Claude | |
dc.date.issued | 2005 | |
dc.identifier.issn | 1155-4339 | |
dc.description.abstractEn | After an investigation of the formation conditions of the intermediate phases existing in the systems Y2O3-P2O5 and Gd2O3-P2O5 (R/P = 4/1, 3/1, 1, 1/2, 1/3 and 1/5 (R = Y or Gd)) the luminescence characteristics of the Eu3+ ion substituted for the Y3+ or Gd3+ ions have been determined. The position of the O-2 -> Eu3+ charge transfer band shifts to higher energies with increasing P content, which results in high quantum efficiencies for several P-rich phosphates. With increasing P content the probability of the electric dipole transitions is reduced, in particular for the hypersensitive 5D a->7 F2 transition. This causes a shift of the colour point to the orange and lengthens the luminescence lifetime. The luminescence characteristics are compared with those of the red phosphors for display. | |
dc.language.iso | en | |
dc.publisher | EDP Sciences | |
dc.title.en | Luminescent properties of Eu3+-doped yttrium or gadolinium phosphates. | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1051/jp4:2005123047 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Journal de Physique IV Proceedings | |
bordeaux.page | p. 259-263 | |
bordeaux.volume | vol. 123 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00022696 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Non spécifiée | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00022696v1 | |
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