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hal.structure.identifierLaboratoire de Cristallographie Thermodynamique
dc.contributor.authorKERFAH, A.
hal.structure.identifierLaboratoire de Cristallographie Thermodynamique
dc.contributor.authorTAÏBI, K.
hal.structure.identifierLaboratoire de Cristallographie Thermodynamique
dc.contributor.authorGUEHRIA-LAIDOUDI, A.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorSIMON, Annie
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorRAVEZ, Jean
dc.date.issued2006
dc.identifier.issn1293-2558
dc.description.abstractEnIn order to investigate the effect of A-site homovalent and heterovalent substitution on phase transition in barium titanium zirconium oxide (Ba(Ti0.7Zr0.3)O3), dielectric studies were performed on ceramics of Ba1−xAx(Ti0.7Zr0.3)O3 and Ba1-xA'2x/3 x/3(Ti0.7Zr0.3)O3 compositions (A=Ca, Sr; A′=Y, La, Bi). A preliminary X-ray powder diffraction study has allowed us to determine the limits of solid solution for each composition. A relaxor behaviour appears whatever the value of x in the solid solution domains. The corresponding relaxor characteristics were determined and discussed according to the substituted cation in the twelve coordination number (12-C.N.) crystallographic site. Such new materials are of interest for environmental-friendly applications.
dc.language.isoen
dc.publisherElsevier
dc.subject.enFerroelectric relaxor
dc.subject.enSolid solution
dc.subject.enChemical composition
dc.subject.enBa1-xAx(Ti0.7Zr0.3)O3
dc.subject.enBa1-xA'2x/3 x/3(Ti0.7Zr0.3)O3
dc.title.enFerroelectric relaxor behaviour of Ba1-xAx(Ti0.7Zr0.3)O3 and Ba1-xA'2x/3 x/3(Ti0.7Zr0.3)O3 compositions (A = Ca, Sr ; A' = Y, La, Bi)
dc.typeArticle de revue
dc.identifier.doi10.1016/j.solidstatesciences.2006.02.033
dc.subject.halChimie/Matériaux
bordeaux.journalSolid State Sciences
bordeaux.pagep. 613-618
bordeaux.volumevol. 8, n° 6
bordeaux.peerReviewedoui
hal.identifierhal-00070913
hal.version1
hal.popularnon
hal.audienceNon spécifiée
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00070913v1
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