Electrochemical lithium insertion into a poly(3,4-ethylenedioxythiophene)PEDOT/V2O5 nanocomposite
| hal.structure.identifier | Centre for Materials for Electronics Technology [C-MET] | |
| dc.contributor.author | VADIVEL MURUGAN, A. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | KWON, Chai-Won | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CAMPET, Guy | |
| hal.structure.identifier | Centre for Materials for Electronics Technology [C-MET] | |
| dc.contributor.author | KALE, B. B. | |
| hal.structure.identifier | Physical and Material Chemistry Division | |
| dc.contributor.author | MADDANIMATH, Trupti | |
| hal.structure.identifier | Physical and Material Chemistry Division | |
| dc.contributor.author | VIJAYAMOHANAN, K. | |
| dc.date.issued | 2002 | |
| dc.identifier.issn | 0378-7753 | |
| dc.description.abstractEn | Ananocomposite comprised of conductive poly(3,4-ethylene dioxythiophene)PEDOT chains interleaved between the layers of crystalline V2O5 powder has been synthesized by direct in situ oxidation. The interlayer spacing of V2O5 expands from 4.32 to 13.84 Å and this interlayer separation is consistent with the existence of a monolayer of PEDOT in the V2O5 framework. The nanocomposite is coupled with a large-area Li foil counter electrode and a Li wire reference electrode in 1 M LiClO4 in a mixture of ethylene and dimethylcorbonate (50/50 by volume), the discharge capacity is ≥300 m Ah g−1 which is larger than that of pristine V2O5. The significant difference in capacity is explained on the basis of lithium ions insertion/de-insertion between the layers of V2O5. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.title.en | Electrochemical lithium insertion into a poly(3,4-ethylenedioxythiophene)PEDOT/V2O5 nanocomposite | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/S0378-7753(01)00992-2 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Journal of Power Sources | |
| bordeaux.page | 1-5 | |
| bordeaux.volume | 105 | |
| bordeaux.issue | 1 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00712876 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| dc.subject.it | Lithiuminsertion | |
| dc.subject.it | PEDOT/V2O5 | |
| dc.subject.it | Nanocomposite | |
| dc.subject.it | Cathode material | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00712876v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Power%20Sources&rft.date=2002&rft.volume=105&rft.issue=1&rft.spage=1-5&rft.epage=1-5&rft.eissn=0378-7753&rft.issn=0378-7753&rft.au=VADIVEL%20MURUGAN,%20A.&KWON,%20Chai-Won&CAMPET,%20Guy&KALE,%20B.%20B.&MADDANIMATH,%20Trupti&rft.genre=article |
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