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Syntheses of raspberrylike silica/polystyrene materials
hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
dc.contributor.author | RECULUSA, Stéphane | |
hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | PONCET-LEGRAND, Céline | |
hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
dc.contributor.author | RAVAINE, Serge | |
hal.structure.identifier | Interactions moléculaires et réactivité chimique et photochimique [IMRCP] | |
dc.contributor.author | MINGOTAUD, Christophe | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | DUGUET, Etienne | |
hal.structure.identifier | Laboratoire de chimie et procédés de polymérisation [LCPP] | |
dc.contributor.author | BOURGEAT-LAMI, Elodie | |
dc.date.issued | 2002 | |
dc.identifier.issn | 0897-4756 | |
dc.description.abstractEn | Raspberrylike hybrid organic−inorganic materials consisting of spherical silica beads supporting smaller polystyrene particles were prepared through a heterophase polymerization process. In a first step, micrometer-sized silica particles were synthesized according to procedures inspired from the literature. In a second step, a poly(ethylene glycol) macromonomer was adsorbed on the surface of the silica beads. Finally, polymerization of styrene was achieved in water with a nonionic surfactant as an emulsifying agent and sodium persulfate as an initiator. Scanning and transmission electron microscopies show that the presence of the macromonomer on the surface of the silica particles is a determining parameter in order to get the raspberrylike morphology. | |
dc.language.iso | en | |
dc.publisher | American Chemical Society | |
dc.subject.en | Polymerization | |
dc.subject.en | Hybrid materials | |
dc.subject.en | Silica | |
dc.subject.en | Polystyrene | |
dc.title.en | Syntheses of raspberrylike silica/polystyrene materials | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1021/cm0116525 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Chemistry of Materials | |
bordeaux.page | 2354-2359 | |
bordeaux.volume | 14 | |
bordeaux.issue | 5 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00715951 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00715951v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemistry%20of%20Materials&rft.date=2002&rft.volume=14&rft.issue=5&rft.spage=2354-2359&rft.epage=2354-2359&rft.eissn=0897-4756&rft.issn=0897-4756&rft.au=RECULUSA,%20St%C3%A9phane&PONCET-LEGRAND,%20C%C3%A9line&RAVAINE,%20Serge&MINGOTAUD,%20Christophe&DUGUET,%20Etienne&rft.genre=article |
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