Na3La9O3(BO3)8, a new oxyborate in the ternary system Na2-La2O3-B2O3 : preparation and crystal structure
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GRAVEREAU, Pierre | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CHAMINADE, Jean-Pierre | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | PECHEV, Stanislav | |
| hal.structure.identifier | Institute of General and Inorganic Chemistry | |
| dc.contributor.author | NIKOLOV, Velin | |
| hal.structure.identifier | Institute of General and Inorganic Chemistry | |
| dc.contributor.author | IVANOVA, Diana | |
| hal.structure.identifier | Institute of General and Inorganic Chemistry | |
| dc.contributor.author | PESHEV, Pavel | |
| dc.date.issued | 2002 | |
| dc.identifier.issn | 1293-2558 | |
| dc.description.abstractEn | A new oxyborate with a composition corresponding to the formula Na3La9O3(BO3)8 has been discovered in the ternary oxide system Na2O-La2O3-B2O3. Single crystals of this compound have been grown by spontaneous crystallization from melts of the constituent binary oxides during slow cooling. The structure of Na3La9O3(BO3)8 has been solved using X-ray data collected on a Nonius Kappa CCD diffractometer (Mo Kα radiation). The unit cell is hexagonal (space group P-62m, Z=1) with a=8.9033(3), c=8.7131(3) Å and V=598.14 Å3. Refinement of 49 parameters using 684 independent reflections with an intensity I>2σ(I) (Friedel not merged for absolute structure determination) results in R1=0.015 (wR2=0.030)... | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Oxyborate of sodium and lanthanum | |
| dc.subject.en | Crystal growth | |
| dc.subject.en | Crystal structure | |
| dc.title.en | Na3La9O3(BO3)8, a new oxyborate in the ternary system Na2-La2O3-B2O3 : preparation and crystal structure | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/S1293-2558(02)01344-4 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Solid State Sciences | |
| bordeaux.page | 993-998 | |
| bordeaux.volume | 4 | |
| bordeaux.issue | 7 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00717777 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00717777v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Solid%20State%20Sciences&rft.date=2002&rft.volume=4&rft.issue=7&rft.spage=993-998&rft.epage=993-998&rft.eissn=1293-2558&rft.issn=1293-2558&rft.au=GRAVEREAU,%20Pierre&CHAMINADE,%20Jean-Pierre&PECHEV,%20Stanislav&NIKOLOV,%20Velin&IVANOVA,%20Diana&rft.genre=article |
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