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hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
hal.structure.identifierDepartement of Chemistry and Faculty of Pharmarcy
dc.contributor.authorLAFON, Adeline
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorTRÉGUER-DELAPIERRE, Mona
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorBAZIN, Damien
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorFAURE, Chrystel
dc.date.issued2012
dc.identifier.issn0303-402X
dc.description.abstractEnThis article describes a general method for the deposition of gold nanoparticles onto solid support based on the use of multilamellar vesicles (MLVs). Gold nanoparticles (nps) synthesized within lipid-based MLVs by UVor γ-irradiation were deposited onto TiO2 powder support. The organic phase from MLVs was removed by calcination leading to high dispersion of naked Au nanoparticles. The resulting particles were investigated using spectrometry, electron microscopy and XPS. The gold nanoparticles were stable and well-separated on the titania surface. It was found that the metal nanoparticles produced by radiolysis have smaller average size and narrower size distribution than those synthesized by photochemical route. After calcinations, the particles tended to enlarge to reach c.a. 18 nm. The gold loading on the titania support could be controlled by changing the gold salt concentration and the MLV-to-TiO2 weight ratio; values of Au-to-Ti ratio up to 44 % could be obtained.
dc.language.isoen
dc.publisherSpringer Verlag
dc.subject.enMultilamellar vesicles
dc.subject.enGold nanoparticles
dc.subject.enTiO2 powder
dc.subject.enSupported catalyst
dc.subject.enPhotolysis
dc.subject.enRadiolysis
dc.title.enDeposit of UV- or γ-synthesized gold nanoparticles on TiO2 powder using lipid-based multilamellar vesicles
dc.typeArticle de revue
dc.identifier.doi10.1007/s00396-012-2616-z
dc.subject.halChimie/Catalyse
bordeaux.journalColloid and Polymer Science
bordeaux.pagepp. 1015-1022
bordeaux.volume290
bordeaux.peerReviewedoui
hal.identifierhal-00734205
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00734205v1
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