Hydrothermal synthesis, structural characterization and thermal, spectroscopic and magnetic properties of the inorganic-organic hydrid phosphate, [C2N2H9)VF(PO4)]
| hal.structure.identifier | Departamento de Química Inorgánica, Facultad de Ciencia y Tecnologia | |
| dc.contributor.author | ALDA, Estibaliz | |
| hal.structure.identifier | Departamento de Química Inorgánica, Facultad de Ciencia y Tecnologia | |
| dc.contributor.author | FERNÁNDEZ, Sergio | |
| hal.structure.identifier | Departamento de Química Inorgánica, Facultad de Ciencia y Tecnologia | |
| dc.contributor.author | MESA, José L. | |
| hal.structure.identifier | Departamento de Mineralogía-Petrología | |
| dc.contributor.author | PIZARRO, José L. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | JUBERA, Veronique | |
| hal.structure.identifier | Departamento de Química Inorgánica, Facultad de Ciencia y Tecnologia | |
| dc.contributor.author | ROJO, Teófilo | |
| dc.date.issued | 2002 | |
| dc.identifier.issn | 0025-5408 | |
| dc.description.abstractEn | The [(C2N2H9)VF(PO4)] compound has been synthesized by hydrothermal techniques under autogeneous pressure at 170°C. The compound was characterized from X-ray powder diffraction data with the Rietveld method. Its crystal structure consists of sheets linked by the ethylenediammonium cations and constructed by chains of VO3F2N octahedra. The thermal study indicates that the compound is stable up to 290°C. In the IR spectrum the bands of both the ethylenediammonium and phosphate ions are observed. From the reflectance diffuse spectrum the Dq and Racah parameters have been calculated. The magnetic measurements indicate the presence of antiferromagnetic interactions. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Microporous materials | |
| dc.subject.en | Thermogravimetric analysis | |
| dc.subject.en | Electronic spectroscopy and magnetic properties | |
| dc.title.en | Hydrothermal synthesis, structural characterization and thermal, spectroscopic and magnetic properties of the inorganic-organic hydrid phosphate, [C2N2H9)VF(PO4)] | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/S0025-5408(02)00938-8 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Materials Research Bulletin | |
| bordeaux.page | 2355-2364 | |
| bordeaux.volume | 37 | |
| bordeaux.issue | 14 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00817265 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00817265v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Materials%20Research%20Bulletin&rft.date=2002&rft.volume=37&rft.issue=14&rft.spage=2355-2364&rft.epage=2355-2364&rft.eissn=0025-5408&rft.issn=0025-5408&rft.au=ALDA,%20Estibaliz&FERN%C3%81NDEZ,%20Sergio&MESA,%20Jos%C3%A9%20L.&PIZARRO,%20Jos%C3%A9%20L.&JUBERA,%20Veronique&rft.genre=article |
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