Ti4+ to Ti3+ conversion of TiO2 uppermost layer by low-temperature vacuum annealing: interest for titanium biomedical applications.
hal.structure.identifier | Biomateriaux et Reparation Tissulaire | |
dc.contributor.author | GUILLEMOT, Fabien | |
hal.structure.identifier | Biomateriaux et Reparation Tissulaire | |
dc.contributor.author | PORTÉ, M. C. | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | LABRUGÈRE, Christine | |
hal.structure.identifier | Biomateriaux et Reparation Tissulaire | |
dc.contributor.author | BAQUEY, Charles | |
dc.date.issued | 2002 | |
dc.identifier.issn | 0021-9797 | |
dc.description.abstractEn | Because of the Ti(3+) defects responsibility for dissociative adsorption of water onto TiO(2) surfaces and due to the hydroxyls influence on the biological behavior of titanium, controlling the Ti(3+) surface defects density by means of low-temperature vacuum annealing is proposed to improve the bone/implant interactions. Experiments have been carried out on Ti-6Al-4V alloys exhibiting a porous surface generated primarily by chemical treatment. XPS investigations have shown that low-temperature vacuum annealing can create a controlled number of Ti(3+) defects (up to 21% Ti(3+)/Ti(4+) at 573 K). High Ti(3+) defect concentration is linked to surface porosity. Such surfaces, exhibiting high hydrophilicity and microporosity, would confer to titanium biomaterials a great ability to interact with surrounding proteins and cells and hence would favor the bone anchorage of as-treated implants. | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.title.en | Ti4+ to Ti3+ conversion of TiO2 uppermost layer by low-temperature vacuum annealing: interest for titanium biomedical applications. | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1006/jcis.2002.8623 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Journal of Colloid and Interface Science | |
bordeaux.page | 75-78 | |
bordeaux.volume | 255 | |
bordeaux.issue | 1 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00817470 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
dc.subject.it | Titanium | |
dc.subject.it | Biomedical application | |
dc.subject.it | Vacuum | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00817470v1 | |
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