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Rational Design of a Photomagnetic Chain: Bridging Single-Molecule Magnets with a Spin-Crossover Complex

hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorABABEI, Rodica
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorPICHON, Céline
hal.structure.identifierInstituto de Ciencia de Materiales de Aragón [Saragoza, España] [ICMA-CSIC]
dc.contributor.authorROUBEAU, Olivier
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorLI, Yang-Guang
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorBRÉFUEL, Nicolas
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorBUISSON, Lionel
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMATHONIÈRE, Corine
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorCLÉRAC, Rodolphe
dc.date.created2013
dc.date.issued2013
dc.identifier.issn0002-7863
dc.description.abstractEnThe spin-crossover complex [Fe(LN5)(CN)2]*H2O (1, LN5 = 2,13-dimethyl-3,6,9-12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene), reported previously by Nelson et al. in 1986, was reinvestigated, and its structure determined by single crystal X-ray diffraction for the first time. The reaction between [MnIII(saltmen)(H2O)]+ and this photomagnetic linker yielded the trinuclear molecular complex [{Mn(saltmen)}2FeHS(LN5)(CN)2](ClO4)2* 0.5CH3OH (2) and the one-dimensional compound [{Mn(saltmen)}2FeLS(LN5)- (CN)2](ClO4)2*0.5C4H10O*0.5H2O (3) depending on the addition order of the reagents (HS: High-Spin; LS: Low-Spin).
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.subject.enPhotomagnetic chain
dc.subject.enSingle-molecule magnets
dc.subject.enSpin-crossover complex
dc.title.enRational Design of a Photomagnetic Chain: Bridging Single-Molecule Magnets with a Spin-Crossover Complex
dc.typeArticle de revue
dc.identifier.doi10.1021/ja407570n
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of the American Chemical Society
bordeaux.pagepp. 14840−14853
bordeaux.volume135
bordeaux.peerReviewedoui
hal.identifierhal-00870774
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00870774v1
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