Photoinduced Single-Molecule Magnet Properties in a Four-Coordinate Iron(II) Spin Crossover Complex.
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MATHONIÈRE, Corine | |
| hal.structure.identifier | Department of Chemistry and Biochemistry | |
| dc.contributor.author | LIN, Hsiu-Jung | |
| dc.contributor.author | SIRETANU, Diana | |
| hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
| dc.contributor.author | CLÉRAC, Rodolphe | |
| hal.structure.identifier | Department of Chemistry and Biochemistry | |
| dc.contributor.author | SMITH, Jeremy M. | |
| dc.date.issued | 2013 | |
| dc.identifier.issn | 0002-7863 | |
| dc.description.abstractEn | The four-coordinate Fe(II) complex, PhB(MesIm)3Fe-N═PPh3 (1) has been previously reported to undergo a thermal spin-crossover (SCO) between high-spin (HS, S = 2) and low-spin (LS, S = 0) states. This complex is photoactive below 20 K, undergoing a photoinduced LS to HS spin state change, as determined by optical reflectivity and photomagnetic measurements. With continuous white light irradiation, 1 displays slow relaxation of the magnetization, i.e. single-molecule magnet (SMM) properties, at temperatures below 5 K. This complex provides a structural template for the design of new photoinduced mononuclear SMMs based on the SCO phenomenon. | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.subject.en | Molecular magnet | |
| dc.subject.en | Complex compounds | |
| dc.subject.en | Spin crossover | |
| dc.title.en | Photoinduced Single-Molecule Magnet Properties in a Four-Coordinate Iron(II) Spin Crossover Complex. | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/ja410643s | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Journal of the American Chemical Society | |
| bordeaux.page | 19083-19086 | |
| bordeaux.volume | 135 | |
| bordeaux.issue | 51 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00923480 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00923480v1 | |
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