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Synthesis, structure and fluorescence of two novel manganese(II) and zinc(II)-1,3,5-benzene tricarboxylate coordination polymers: Extended 3D supramolecular architectures stabilised by hydrogen bonding

hal.structure.identifierDepartment of Chemistry
dc.contributor.authorMAJUMDER, Arpi
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorSHIT, Shyamapada
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorROY CHOUDHURY, Chirantan
hal.structure.identifierSchool of Chemistry
dc.contributor.authorBATTEN, Stuart R.
hal.structure.identifierLaboratoire des Multimatériaux et Interfaces [LMI]
dc.contributor.authorPILET, Guillaume
hal.structure.identifierLaboratoire des Multimatériaux et Interfaces [LMI]
dc.contributor.authorLUNEAU, Dominique
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDARO, Nathalie
hal.structure.identifierLaboratoire de chimie de coordination [LCC]
dc.contributor.authorSUTTER, Jean-Pascal
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorCHATTOPADHYAY, Nitin
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorMITRA, Samiran
dc.date.issued2005
dc.identifier.issn0020-1693
dc.description.abstractEnTwo new coordination polymers [Mn(H2btc)(phen)(H2O)2]H2btc · H2O n (1) [H3btc = 1,3,5-benzene tricarboxylic acid, phen = phenanthroline] and [Zn3(btc)2(H2O)8](H2O)4 n (2) have been synthesised and structurally characterised. Both the complexes crystallise as 1D chain, which further propagates through ligand-based hydrogen bonding interactions into a 3D supramolecular architecture. Supramolecular framework of 1 is constructed by [Mn(H2btc)(phen)(H2O)2]+ as well as the constituent materials–uncoordinated H2btc− and water molecules. Complex 2 exists as a corrugated chain with both the bridging and terminal Zn2+ ions and each zinc centre is coordinated to four water molecules. Both 1 and 2 are stacked by mutual π-stacking of the ligands and exhibit strong fluorescence emission band at 414 and 400 nm, respectively.
dc.language.isoen
dc.publisherElsevier
dc.subject.enCoordination polymers with Mn(II) and Zn(II)
dc.subject.enSupramolecular frameworks
dc.subject.enCrystal structures
dc.subject.enFluorescence
dc.title.enSynthesis, structure and fluorescence of two novel manganese(II) and zinc(II)-1,3,5-benzene tricarboxylate coordination polymers: Extended 3D supramolecular architectures stabilised by hydrogen bonding
dc.typeArticle de revue
dc.identifier.doi10.1016/j.ica.2005.07.002
dc.subject.halChimie/Matériaux
bordeaux.journalInorganica Chimica Acta
bordeaux.page3855-3864
bordeaux.volume358
bordeaux.issue13
bordeaux.peerReviewedoui
hal.identifierhal-00097506
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00097506v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Inorganica%20Chimica%20Acta&rft.date=2005&rft.volume=358&rft.issue=13&rft.spage=3855-3864&rft.epage=3855-3864&rft.eissn=0020-1693&rft.issn=0020-1693&rft.au=MAJUMDER,%20Arpi&SHIT,%20Shyamapada&ROY%20CHOUDHURY,%20Chirantan&BATTEN,%20Stuart%20R.&PILET,%20Guillaume&rft.genre=article


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