A truly multifunctional heterocycle: Iminophosphorane, N,P chelate, and dihydropyridine
hal.structure.identifier | Centre d'Etudes Nucléaires de Bordeaux Gradignan [CENBG] | |
dc.contributor.author | SMITH, D.A. | |
dc.contributor.author | BATSANOV, A.S. | |
hal.structure.identifier | Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux [IPREM] | |
dc.contributor.author | MIQUEU, Karinne | |
hal.structure.identifier | Institut pluridisciplinaire de recherche sur l'environnement et les matériaux [IPREM] | |
dc.contributor.author | SOTIROPOULOS, Jean-Marc | |
hal.structure.identifier | DEPARTMENT OF CHEMISTRY | |
dc.contributor.author | APPERLEY, D.C. | |
hal.structure.identifier | Chemistry Department | |
dc.contributor.author | HOWARD, J.A.K. | |
hal.structure.identifier | DEPARTMENT OF CHEMISTRY | |
dc.contributor.author | DYER, P.W. | |
dc.date.issued | 2008 | |
dc.identifier.issn | 1433-7851 | |
dc.description.abstractEn | (Chemical Equation Presented) Three in one: The anellated σ4-1λ5-[1,3,2]diazaphosphole 2 exists in tautomeric equilibrium with isomer 1 (see scheme) and undergoes three completely different types of reaction: trimethyl aluminum binds at the N terminus of the P=N bond with ring retention, the dihydropyridine fragment reacts with an activated acetylene in a pseudo-[2+2] cycloaddition, and P-N bond cleavage is possible with RhI. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA. | |
dc.language.iso | en | |
dc.publisher | Wiley-VCH Verlag | |
dc.title.en | A truly multifunctional heterocycle: Iminophosphorane, N,P chelate, and dihydropyridine | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1002/anie.200803373 | |
dc.subject.hal | Chimie/Catalyse | |
dc.subject.hal | Chimie/Chimie de coordination | |
dc.subject.hal | Chimie/Chimie organique | |
dc.subject.hal | Chimie/Polymères | |
dc.subject.hal | Chimie/Chimie théorique et/ou physique | |
bordeaux.journal | Angewandte Chemie International Edition | |
bordeaux.page | 8674-8677 | |
bordeaux.volume | 47 | |
bordeaux.issue | 45 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-01613259 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-01613259v1 | |
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