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A truly multifunctional heterocycle: Iminophosphorane, N,P chelate, and dihydropyridine

hal.structure.identifierCentre d'Etudes Nucléaires de Bordeaux Gradignan [CENBG]
dc.contributor.authorSMITH, D.A.
dc.contributor.authorBATSANOV, A.S.
hal.structure.identifierInstitut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux [IPREM]
dc.contributor.authorMIQUEU, Karinne
hal.structure.identifierInstitut pluridisciplinaire de recherche sur l'environnement et les matériaux [IPREM]
dc.contributor.authorSOTIROPOULOS, Jean-Marc
hal.structure.identifierDEPARTMENT OF CHEMISTRY
dc.contributor.authorAPPERLEY, D.C.
hal.structure.identifierChemistry Department
dc.contributor.authorHOWARD, J.A.K.
hal.structure.identifierDEPARTMENT OF CHEMISTRY
dc.contributor.authorDYER, P.W.
dc.date.issued2008
dc.identifier.issn1433-7851
dc.description.abstractEn(Chemical Equation Presented) Three in one: The anellated σ4-1λ5-[1,3,2]diazaphosphole 2 exists in tautomeric equilibrium with isomer 1 (see scheme) and undergoes three completely different types of reaction: trimethyl aluminum binds at the N terminus of the P=N bond with ring retention, the dihydropyridine fragment reacts with an activated acetylene in a pseudo-[2+2] cycloaddition, and P-N bond cleavage is possible with RhI. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.title.enA truly multifunctional heterocycle: Iminophosphorane, N,P chelate, and dihydropyridine
dc.typeArticle de revue
dc.identifier.doi10.1002/anie.200803373
dc.subject.halChimie/Catalyse
dc.subject.halChimie/Chimie de coordination
dc.subject.halChimie/Chimie organique
dc.subject.halChimie/Polymères
dc.subject.halChimie/Chimie théorique et/ou physique
bordeaux.journalAngewandte Chemie International Edition
bordeaux.page8674-8677
bordeaux.volume47
bordeaux.issue45
bordeaux.peerReviewedoui
hal.identifierhal-01613259
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01613259v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.date=2008&rft.volume=47&rft.issue=45&rft.spage=8674-8677&rft.epage=8674-8677&rft.eissn=1433-7851&rft.issn=1433-7851&rft.au=SMITH,%20D.A.&BATSANOV,%20A.S.&MIQUEU,%20Karinne&SOTIROPOULOS,%20Jean-Marc&APPERLEY,%20D.C.&rft.genre=article


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