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Enantioselective Crystallization of Diglycerol Dicarbonate: Impact of the Microstructure on Polyhydroxyurethane Properties.
MAGLIOZZI, Fiona
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
SCALI, Arthur
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Leer más >
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
MAGLIOZZI, Fiona
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
SCALI, Arthur
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
GRAU, Etienne
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
CRAMAIL, Henri
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
< Leer menos
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Article de revue
Este ítem está publicado en
Macromolecular Rapid Communications. 2020-11-25p. e2000533
Resumen en inglés
Bicylic carbonates are precursors employed in non-isocyanate polyurethane syntheses, namely polyhydroxyurethanes (PHUs) and, among them, ether-activated biobased diglycerol dicarbonate (DGDC) is widely investigated. Herein, ...Leer más >
Bicylic carbonates are precursors employed in non-isocyanate polyurethane syntheses, namely polyhydroxyurethanes (PHUs) and, among them, ether-activated biobased diglycerol dicarbonate (DGDC) is widely investigated. Herein, the original separation of DGDC stereoisomers, thanks to a recrystallization procedure, leading to enantiomers having different crystal lattices, that is, square transparent crystals and needle-like structures, respectively, is reported. In this study, the separation and the characterization of the two crystal structures is first discussed and, second, the impact of the stereochemistry of DGDC on the corresponding PHUs properties is investigated.< Leer menos
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