POIVET, S.; FABRE, Pierre-Antoine; NALLET, Frederic; SCHIERHOLZ, K.; ABRAHAM, G.; PAPON, Eric; GNANOU, Yves; OBER, R.; GUERRET, Olivier; EL-BOUNIA, N.E.

doi:10.1140/epje/i2005-10130-7

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POIVET, S.
Centre de recherches Paul Pascal [CRPP]

FABRE, Pierre-Antoine
Centre de recherches Paul Pascal [CRPP]

NALLET, Frederic

Centre de recherches Paul Pascal [CRPP]

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European Physical Journal E: Soft matter and biological physics. 2006, vol. 20, p. p. 273-287

EDP Sciences: EPJ

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We study asymmetric block copolymers with the simple diblock AB architecture, in the case where the longer block A is both hydrophobic and "soft", whereas the shorter block B is hydrophilic and "hard". Materials with such a particular combination of physico-chemical and mechanical properties have distinctive advantages, in particular for designing water-compatible adhesive materials. The phase diagram is established, combining NMR and SAXS characterisations of the materials. The swelling with water is monitored through gravimetry and "time-resolved" SAXS. Indications of maintained adhesive properties in a wet environment are given.< Leer menos

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macromolecular and polymers solutions

copolymers

polymers on surfaces

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Amphiphilic diblock copolymers with adhesive properties: I. Structure and swelling with water

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