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Cross-linking of polybutadiene at the air/water interface: Toward an easy access to two-dimensional polymeric materials

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorMATMOUR, Rachid
hal.structure.identifierDepartment of Chemistry and Center for Macromolecular Science and Engineering
dc.contributor.authorJONCHERAY, Thomas J.
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorGNANOU, Yves
hal.structure.identifierDepartment of Chemistry and Center for Macromolecular Science and Engineering
dc.contributor.authorDURAN, Randolph S.
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2007
dc.identifier.issn0021-9797
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20829
dc.description.abstractEnA novel approach to two-dimensionally crosslink polydienes at the air/water interface is proposed. The acid-catalyzed condensation of the triethoxysilane pendant groups of triethoxysilane-functionalized polybutadiene chains at the air/water interface successfully led to the formation of an insoluble crosslinked material which could be directly removed from the water surface. The efficiency of the cross-linking reaction was demonstrated through surface pressure measurements such as surface pressure-mean molecular area isotherms recorded at different reaction times and isobar experiments for different subphase pH values. The evolution of the monolayer topography during cross-linking was studied by atomic force microscopy imaging of the Langmuir-Blodgett films. (C) 2007 Elsevier Inc. All rights reserved
dc.language.isoen
dc.publisherElsevier
dc.subject.entriethoxysilane
dc.subject.enair/water interface
dc.subject.enLangmuir-Blodgett films
dc.subject.enpolybutadiene
dc.subject.entwo-dimensional cross-linking
dc.title.enCross-linking of polybutadiene at the air/water interface: Toward an easy access to two-dimensional polymeric materials
dc.typeArticle de revue
dc.identifier.doi10.1016/j.jcis.2007.02.065
dc.subject.halChimie/Polymères
bordeaux.journalJournal of Colloid and Interface Science
bordeaux.page315-321
bordeaux.volume311
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue1
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00275932
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00275932v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Colloid%20and%20Interface%20Science&rft.date=2007&rft.volume=311&rft.issue=1&rft.spage=315-321&rft.epage=315-321&rft.eissn=0021-9797&rft.issn=0021-9797&rft.au=MATMOUR,%20Rachid&JONCHERAY,%20Thomas%20J.&GNANOU,%20Yves&DURAN,%20Randolph%20S.&rft.genre=article


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