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Functional crosslinked polymer particles synthesized by precipitation polymerization for liquid chromatography

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorPERRIER-CORNET, Romain
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorHÉROGUEZ, Valérie
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorTHIENPONT, Annie
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorBABOT, Odile
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorTOUPANCE, Thierry
dc.date.accessioned2020
dc.date.available2020
dc.date.created2007
dc.date.issued2008
dc.identifier.issn0021-9673
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20783
dc.description.abstractEnHighly crosslinked functional polymer particles with narrow size distribution have been produced by precipitation copolymerization of divinylbenzene, ethylene glycol dimethacrylate and vinylbenzyl chloride using a simple reflux protocol. After establishing the satisfactory synthesis conditions, we produced uniform chlorobenzyl particles with different size depending on the polymerization times. The porosity of those particles was modulated from microporous to mesoporous structure by using various porogens such as toluene, dodecanol, cyclohexanol and polypropylene glycol. These particles were tested as stationary phase in high-performance liquid chromatography for the separation of polycyclic aromatic hydrocarbons in reversed-phase mode. The separation was observed even for elution 100% organic (methanol) without any participation of water fraction in the eluent composition. The influences of particles size, specific surface area and packing conditions on the separation behavior were investigated. (c) 2007 Elsevier B.V. All rights reserved.
dc.language.isoen
dc.publisherElsevier
dc.subject.enporous particles
dc.subject.enfunctional crosslinked particles
dc.subject.enpolymer stationary phases
dc.subject.enprecipitation polymerization
dc.subject.enliquid chromatography
dc.title.enFunctional crosslinked polymer particles synthesized by precipitation polymerization for liquid chromatography
dc.typeArticle de revue
dc.identifier.doi10.1016/j.chroma.2007.09.064
dc.subject.halChimie/Polymères
bordeaux.journalJournal of Chromatography A
bordeaux.page2-8
bordeaux.volume1179
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue1
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00340316
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00340316v1
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