Poly(3-hexylthiophene) based block copolymers prepared by "click" chemistry
dc.rights.license | open | |
hal.structure.identifier | Laboratoire de l'intégration, du matériau au système [IMS] | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
dc.contributor.author | URIEN, Mathieu | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
dc.contributor.author | EROTHU, Harikrishna | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
dc.contributor.author | CLOUTET, Eric
IDREF: 151048681 | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
dc.contributor.author | HIORNS, Roger C. | |
hal.structure.identifier | Laboratoire de l'intégration, du matériau au système [IMS] | |
dc.contributor.author | VIGNAU, Laurence | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
dc.contributor.author | CRAMAIL, Henri | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.created | 2008 | |
dc.date.issued | 2008 | |
dc.identifier.issn | 0141-8130 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20782 | |
dc.description.abstractEn | pi-Conjugated block copolymers have been prepared from terminal azide functionalized polystyrenes (PS) and alkyne functionalized poly (3-hexylthiophene)s (P3HT) via a copper(I) catalyzed Huisgen [3 + 2] dipolar cycloaddition reaction. The functionalized alpha-azido-PS homopolymer was prepared by atom transfer radical polymerization from a specifically designed initiator bearing the azide function, whereas omega-ethynyl-P3HT and a,alpha,omega-pentynyl-P3HT were synthesized by a modified Grignard metathesis polymerization using alkynyl Grignard derivatives. The electronic environment of the alkynyl end groups was shown to be decisive in determining triazole ring formation. | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.subject.en | ckick chemistry | |
dc.subject.en | cycloaddition | |
dc.subject.en | heterojunction solar-cells | |
dc.subject.en | regioregular poly(3-alkylthiophenes) | |
dc.subject.en | photovoltaic devices | |
dc.subject.en | diblock copolymers | |
dc.title.en | Poly(3-hexylthiophene) based block copolymers prepared by "click" chemistry | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1021/ma800659a | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | International Journal of Biological Macromolecules | |
bordeaux.page | 7033-7040 | |
bordeaux.volume | 41 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.issue | 19 | |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00340347 | |
hal.version | 1 | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00340347v1 | |
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