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hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorURIEN, Mathieu
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorEROTHU, Harikrishna
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorHIORNS, Roger C.
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorVIGNAU, Laurence
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCRAMAIL, Henri
dc.date.accessioned2020
dc.date.available2020
dc.date.created2008
dc.date.issued2008
dc.identifier.issn0141-8130
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20782
dc.description.abstractEnpi-Conjugated block copolymers have been prepared from terminal azide functionalized polystyrenes (PS) and alkyne functionalized poly (3-hexylthiophene)s (P3HT) via a copper(I) catalyzed Huisgen [3 + 2] dipolar cycloaddition reaction. The functionalized alpha-azido-PS homopolymer was prepared by atom transfer radical polymerization from a specifically designed initiator bearing the azide function, whereas omega-ethynyl-P3HT and a,alpha,omega-pentynyl-P3HT were synthesized by a modified Grignard metathesis polymerization using alkynyl Grignard derivatives. The electronic environment of the alkynyl end groups was shown to be decisive in determining triazole ring formation.
dc.language.isoen
dc.publisherElsevier
dc.subject.enckick chemistry
dc.subject.encycloaddition
dc.subject.enheterojunction solar-cells
dc.subject.enregioregular poly(3-alkylthiophenes)
dc.subject.enphotovoltaic devices
dc.subject.endiblock copolymers
dc.title.enPoly(3-hexylthiophene) based block copolymers prepared by "click" chemistry
dc.typeArticle de revue
dc.identifier.doi10.1021/ma800659a
dc.subject.halChimie/Polymères
bordeaux.journalInternational Journal of Biological Macromolecules
bordeaux.page7033-7040
bordeaux.volume41
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue19
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00340347
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00340347v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=International%20Journal%20of%20Biological%20Macromolecules&rft.date=2008&rft.volume=41&rft.issue=19&rft.spage=7033-7040&rft.epage=7033-7040&rft.eissn=0141-8130&rft.issn=0141-8130&rft.au=URIEN,%20Mathieu&EROTHU,%20Harikrishna&CLOUTET,%20Eric&HIORNS,%20Roger%20C.&VIGNAU,%20Laurence&rft.genre=article


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