Design of PEO-based ruthenium carbene for aqueous metathesis polymerization. Synthesis by the "macromonomer method" and application in the miniemulsion metathesis polymerization of norbornene
HÉROGUEZ, Valérie
Laboratoire de Chimie des polymères organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Laboratoire de Chimie des polymères organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
HÉROGUEZ, Valérie
Laboratoire de Chimie des polymères organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
< Reduce
Laboratoire de Chimie des polymères organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Language
en
Article de revue
This item was published in
Journal of Polymer Science Part A: Polymer Chemistry. 2006, vol. 44, n° 9, p. 2784-2793
Wiley
English Abstract
Novel water-soluble ruthenium carbene complexes with finely tuned structure and properties in solution are reported. These ruthenium-based initiators were found to exhibit great catalytic activity in aqueous miniemulsion ...Read more >
Novel water-soluble ruthenium carbene complexes with finely tuned structure and properties in solution are reported. These ruthenium-based initiators were found to exhibit great catalytic activity in aqueous miniemulsion ring-opening metathesis polymerization of norbornene. Stable particles of polynorbornene could be generated in the 200-250 nm size range stabilized with a nonionic surfactant (polystyrene-b-poly(ethylene oxide)).Read less <
English Keywords
miniemulsion polymerization
ring-opening metathesis polymerization
water-soluble carbene
macromonomers
Origin
Hal imported