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dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorCARLOTTI, Stéphane
hal.structure.identifierPolymer Laboratory [BASF]
dc.contributor.authorDESBOIS, Philippe
hal.structure.identifierPolymer Laboratory [BASF]
dc.contributor.authorWARZELHAN, Volker
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorDEFFIEUX, Alain
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2009
dc.identifier.issn0032-3861
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20616
dc.description.abstractEnThe possibilities to achieve a quantitative living-like anionic polymerization of styrene and dienes in the absence of solvent and at elevated temperature and using inexpensive initiating systems were explored to make the anionic polymerization competitive with industrial radical processes and allow the industrial production of anionic polystyrene (PS). It implied at first to control the reactivity and stability of initiating and propagating active species in such unusual operating conditions. To achieve these goals the so-called styrene and butadiene ''Retarded Anionic Polymerization'' (RAP) have been developed. This review focuses on the description of different bimetallic anionic polymerization systems which are able to approach or fulfill the industrial conditions for styrene and dienes anionic polymerizations.
dc.language.isoen
dc.publisherElsevier
dc.subject.enate complex
dc.subject.enbutadiene
dc.subject.enstyrene
dc.subject.enretarded anionic polymerization
dc.title.enRetarded anionic polymerization (RAP) of styrene and dienes
dc.typeArticle de revue
dc.identifier.doi10.1016/j.polymer.2009.05.015
dc.subject.halChimie/Polymères
bordeaux.journalPolymer
bordeaux.page3057-3067
bordeaux.volume50
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue14
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00400771
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00400771v1
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