Living polymerization of olefins initiated by nickel catalysts
dc.rights.license | open | |
hal.structure.identifier | Brno Univ Technol, Inst Mat Chem | |
dc.contributor.author | MERNA, Jan | |
hal.structure.identifier | Brno Univ Technol, Inst Mat Chem | |
dc.contributor.author | HERMANOVA, Sona | |
hal.structure.identifier | Brno Univ Technol, Inst Mat Chem | |
dc.contributor.author | CIHLAR, Jaroslav | |
hal.structure.identifier | Brno Univ Technol, Inst Mat Chem | |
dc.contributor.author | KUCERA, Miloslav | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
dc.contributor.author | CRAMAIL, Henri | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
dc.contributor.author | DEFFIEUX, Alain | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.issued | 2005 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20606 | |
dc.description.abstractEn | Contribution reports for the first time on living-like polymerization of olefins initiated by several diimine complexes of nickel. Further, unusual kinetics of these systems is observed revealing decrease of propagation rate constant values with increase of initial monomer concentration. This behavior can be correlated with suggested mechanism, which includes competition between isomerization (chain walking) and propagation reaction, and is documented by changes in polymer microstructure. | |
dc.language.iso | en | |
dc.title.en | Living polymerization of olefins initiated by nickel catalysts | |
dc.type | Article de revue | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | Chemicke Listy | |
bordeaux.page | s373-s376 | |
bordeaux.volume | 99 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.issue | 14 | |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00406269 | |
hal.version | 1 | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00406269v1 | |
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