Synthesis of Polyaniline Nano-Objects Using Poly(vinyl alcohol)-, Poly(ethylene oxide)-, and Poly[(N-vinyl pyrrolidone)-co-(vinyl alcohol)]-Based Reactive Stabilizers
MUMTAZ, Muhammad
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
CLOUTET, Eric
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
See more >
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
MUMTAZ, Muhammad
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
CLOUTET, Eric
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
CRAMAIL, Henri
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
< Reduce
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Language
en
Article de revue
This item was published in
Langmuir. 2009, vol. 25, n° 23, p. 13569-13580
American Chemical Society
English Abstract
Well-defined polyaniline (PANI) nano-objects (e.g., spheres, peanuts, rice grains, corals, and fibers) were prepared by aniline dispersion polymerization in aqueous media in the presence of various reactive polymer stabilizers ...Read more >
Well-defined polyaniline (PANI) nano-objects (e.g., spheres, peanuts, rice grains, corals, and fibers) were prepared by aniline dispersion polymerization in aqueous media in the presence of various reactive polymer stabilizers (i.e., poly(ethylene oxide) (PEO), poly(vinyl alcohol) (PVA), and poly[(N-vinyl pyrrolidone)-co-(vinyl alcohol)] (PNVP-co-PVA)). It was found that the shape, size, and conductivity of resulting PANI nanostructures depended on the acidic conditions along with the nature, molecular weight, and functionality of the reactive stabilizer. PANI samples were analyzed by X-ray photoelectron spectroscopy (XPS), dynamic scanning calorimetry (DSC), thermogravimetric analysis (TGA), UV-visible and FTIR spectroscopy, transmission electron microscopy (TEM), atomic force microscopy (AFM), and conductivity measurements. PANI samples show conductivities between 5 x 10(-3) to 5 x 10(-1) S/cm depending upon the experimental conditions. The best conductivities were obtained when aniline was polymerized in a mixture of DMSO and water (2:3) in the presence of PEO- or PNVP-co-PVA-based reactive stabilizers.Read less <
English Keywords
COMPOSITE
PARTICLES
LIGHT-SCATTERING
RAY PHOTOELECTRON-SPECTROSCOPY
CONDUCTING POLYMER COLLOIDS
DISPERSION POLYMERIZATION
ELECTRICAL-CONDUCTIVITY
CORROSION PROTECTION
MORPHOLOGY
FILMS
Origin
Hal imported