Metal-free and solvent-free access to alpha,omega-heterodifunctionalized poly(propylene oxide)s by N-heterocyclic carbene-induced ring opening polymerization.
TATON, Daniel
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
< Reduce
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Language
en
Article de revue
This item was published in
Chemical Communications. 2010, vol. 46, n° 18, p. 3203-3205
Royal Society of Chemistry
English Abstract
A N-heterocyclic carbene, namely, 1,3-bis-(diisopropyl)imidazol-2-ylidene either directly initiates or catalyzes the metal-free ring opening polymerization of neat propylene oxide at 50 degrees C, affording well-defined ...Read more >
A N-heterocyclic carbene, namely, 1,3-bis-(diisopropyl)imidazol-2-ylidene either directly initiates or catalyzes the metal-free ring opening polymerization of neat propylene oxide at 50 degrees C, affording well-defined alpha,omega-heterodifunctionalized poly(propylene oxide) oligomers.Read less <
English Keywords
poly(propylene oxide)
ring opening polymerization
organocatalysis
N-heterocyclic carbenes
Origin
Hal imported