Afficher la notice abrégée

Synthesis of glycerin carbonate-based intermediates using thiol-ene chemistry and isocyanate free polyhydroxyurethanes therefrom

dc.rights.licenseopen
hal.structure.identifierInstitut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
dc.contributor.authorBENYAHYA, Sofia
hal.structure.identifierInstitut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
dc.contributor.authorDESROCHES, Myriam
hal.structure.identifierInstitut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
dc.contributor.authorAUVERGNE, Rémi
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorCARLOTTI, Stéphane
hal.structure.identifierInstitut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
dc.contributor.authorCAILLOL, Sylvain
hal.structure.identifierInstitut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
dc.contributor.authorBOUTEVIN, Bernard
dc.date.accessioned2020
dc.date.available2020
dc.date.created2011
dc.date.issued2011
dc.identifier.issn1759-9954
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20565
dc.description.abstractEnA new synthesis of 4-[(prop-2-en-1-yloxy)methyl]-1,3-dioxolan-2-one (AGC) was performed by Williamson ether synthesis from 4-(hydroxymethyl)-1,3-dioxolan-2-one. Dicyclocarbonates were synthesized by UV thiol-ene coupling of allyl-cyclocarbonate with a 2,20-oxydiethanethiol. This photochemical thiol-ene reaction was carried out under air, with neither solvent nor photoinitiator. The products, obtained with high yield, were characterized by 1H NMR and FTIR analysis. The synthesized dicyclocarbonates were used without purification to synthesize polyhydroxyurethanes without isocyanate by step growth polyaddition with 1,10-diaminodecane. The synthesized polyhydroxyurethanes were characterized by 1H NMR, FTIR, ATG and DSC analysis. These polyhydroxyurethanes exhibited glass transition temperatures from -31°C to -14°C, molecular weight from 7,000 g/mol to 9000 g/mol and degradation temperature for 5% of weight loss (Td 5%) between 227°C and 250°C.
dc.language.isoen
dc.publisherRoyal Society of Chemistry - RSC
dc.subject.enbiobased polymers
dc.subject.ennon isocyanates polyurethanes
dc.subject.enthiol-ene
dc.title.enSynthesis of glycerin carbonate-based intermediates using thiol-ene chemistry and isocyanate free polyhydroxyurethanes therefrom
dc.typeArticle de revue
dc.identifier.doi10.1039/c1py00289a
dc.subject.halChimie/Polymères
bordeaux.journalPolymer Chemistry
bordeaux.page2661-2667
bordeaux.volume2
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00631583
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00631583v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polymer%20Chemistry&rft.date=2011&rft.volume=2&rft.spage=2661-2667&rft.epage=2661-2667&rft.eissn=1759-9954&rft.issn=1759-9954&rft.au=BENYAHYA,%20Sofia&DESROCHES,%20Myriam&AUVERGNE,%20R%C3%A9mi&CARLOTTI,%20St%C3%A9phane&CAILLOL,%20Sylvain&rft.genre=article


Fichier(s) constituant ce document

FichiersTailleFormatVue

Il n'y a pas de fichiers associés à ce document.

Ce document figure dans la(les) collection(s) suivante(s)

Afficher la notice abrégée