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Polymer support of "single-site" catalysts for heterogeneous olefin polymerization

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorHEURTEFEU, Bertrand
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorBOUILHAC, Cécile
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorTATON, Daniel
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorDEFFIEUX, Alain
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCRAMAIL, Henri
dc.date.accessioned2020
dc.date.available2020
dc.date.created2011
dc.date.issued2011
dc.identifier.issn0079-6700
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20545
dc.description.abstractEnThe discovery of metallocenes and post-metallocenes has revived olefin polymer chemistry as these single-site catalysts enable the production of (co)polyolefins with tunable molecular structures, stereochemistries and molecular weight distributions. To be used in industry, however, such catalysts have to be manipulated under conditions already common to existing polyolefin production processes. This means, in particular, that their heterogenization is required to produce beads of polyolefins and prevent reactor fouling, and this in turn leads to the use of supports for these catalysts. The large majority of supports currently used in industry are inorganic-based, with silica being the most important. Organic supports are also of interest as they are expected to be more versatile and less expensive. This review presents a detailed survey of the different routes to immobilizing single-site catalysts on organic supports. The various methods as well as the different types of supports are described. The influence of the organic support on the catalytic activity and main features of the thus formed polyolefin viz, molecular weight, dispersity and morphology, are also considered.
dc.language.isoen
dc.publisherElsevier
dc.subject.enPolyolefins
dc.subject.enOrganic-supports
dc.subject.enSingle-site catalysts
dc.title.enPolymer support of "single-site" catalysts for heterogeneous olefin polymerization
dc.typeArticle de revue
dc.identifier.doi10.1016/j.progpolymsci.2010.09.002
dc.subject.halChimie/Polymères
bordeaux.journalProgress in Polymer Science
bordeaux.page89-126
bordeaux.volume36
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue1
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00677766
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00677766v1
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