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hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorHEURTEFEU, Bertrand
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorIBARBOURE, Emmanuel
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCRAMAIL, Henri
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2012
dc.identifier.issn1759-9954
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20462
dc.description.abstractEnIn this work, we report the self-assembly in heptane of omega-dimethyl ammonium tetrakis-pentafluorophenyl borate polyisoprenes into micellar aggregates and the use of these nano-objects to support alkylated metallocenes toward ethylene polymerization. Dynamic light scattering was used to demonstrate the self-assembly and the formation of the micellar structures having a core of polar dimethyl ammonium tetrakis-pentafluorophenyl borate moieties, and a corona of polyisoprene (PI). The latter were then used as organic supports for alkylated metallocenes to produce unprecedented millimetric polyethylene beads without loss of catalytic activity.
dc.language.isoen
dc.publisherRoyal Society of Chemistry - RSC
dc.subject.enSTAR-LIKE POLYSTYRENES
dc.subject.enETHYLENE POLYMERIZATION
dc.subject.enOLEFIN POLYMERIZATION
dc.subject.enCATALYTIC-SYSTEM
dc.subject.enSUPPORTS
dc.title.enomega-Dimethyl ammonium tetrakis-pentafluorophenyl borate polyisoprene as an organic template for alkylated metallocenes toward the synthesis of polyethylene beads
dc.typeArticle de revue
dc.identifier.doi10.1039/c2py00588c
dc.subject.halChimie/Polymères
bordeaux.journalPolymer Chemistry
bordeaux.page1133-1136
bordeaux.volume3
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue5
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00758756
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00758756v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polymer%20Chemistry&rft.date=2012&rft.volume=3&rft.issue=5&rft.spage=1133-1136&rft.epage=1133-1136&rft.eissn=1759-9954&rft.issn=1759-9954&rft.au=HEURTEFEU,%20Bertrand&IBARBOURE,%20Emmanuel&CRAMAIL,%20Henri&rft.genre=article


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