omega-Dimethyl ammonium tetrakis-pentafluorophenyl borate polyisoprene as an organic template for alkylated metallocenes toward the synthesis of polyethylene beads
dc.rights.license | open | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
dc.contributor.author | HEURTEFEU, Bertrand | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
dc.contributor.author | IBARBOURE, Emmanuel | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
dc.contributor.author | CRAMAIL, Henri | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.issued | 2012 | |
dc.identifier.issn | 1759-9954 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20462 | |
dc.description.abstractEn | In this work, we report the self-assembly in heptane of omega-dimethyl ammonium tetrakis-pentafluorophenyl borate polyisoprenes into micellar aggregates and the use of these nano-objects to support alkylated metallocenes toward ethylene polymerization. Dynamic light scattering was used to demonstrate the self-assembly and the formation of the micellar structures having a core of polar dimethyl ammonium tetrakis-pentafluorophenyl borate moieties, and a corona of polyisoprene (PI). The latter were then used as organic supports for alkylated metallocenes to produce unprecedented millimetric polyethylene beads without loss of catalytic activity. | |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry - RSC | |
dc.subject.en | STAR-LIKE POLYSTYRENES | |
dc.subject.en | ETHYLENE POLYMERIZATION | |
dc.subject.en | OLEFIN POLYMERIZATION | |
dc.subject.en | CATALYTIC-SYSTEM | |
dc.subject.en | SUPPORTS | |
dc.title.en | omega-Dimethyl ammonium tetrakis-pentafluorophenyl borate polyisoprene as an organic template for alkylated metallocenes toward the synthesis of polyethylene beads | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1039/c2py00588c | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | Polymer Chemistry | |
bordeaux.page | 1133-1136 | |
bordeaux.volume | 3 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.issue | 5 | |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00758756 | |
hal.version | 1 | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00758756v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polymer%20Chemistry&rft.date=2012&rft.volume=3&rft.issue=5&rft.spage=1133-1136&rft.epage=1133-1136&rft.eissn=1759-9954&rft.issn=1759-9954&rft.au=HEURTEFEU,%20Bertrand&IBARBOURE,%20Emmanuel&CRAMAIL,%20Henri&rft.genre=article |
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