omega-Dimethyl ammonium tetrakis-pentafluorophenyl borate polyisoprene as an organic template for alkylated metallocenes toward the synthesis of polyethylene beads
CRAMAIL, Henri
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
CRAMAIL, Henri
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
< Reduce
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Language
en
Article de revue
This item was published in
Polymer Chemistry. 2012, vol. 3, n° 5, p. 1133-1136
Royal Society of Chemistry - RSC
English Abstract
In this work, we report the self-assembly in heptane of omega-dimethyl ammonium tetrakis-pentafluorophenyl borate polyisoprenes into micellar aggregates and the use of these nano-objects to support alkylated metallocenes ...Read more >
In this work, we report the self-assembly in heptane of omega-dimethyl ammonium tetrakis-pentafluorophenyl borate polyisoprenes into micellar aggregates and the use of these nano-objects to support alkylated metallocenes toward ethylene polymerization. Dynamic light scattering was used to demonstrate the self-assembly and the formation of the micellar structures having a core of polar dimethyl ammonium tetrakis-pentafluorophenyl borate moieties, and a corona of polyisoprene (PI). The latter were then used as organic supports for alkylated metallocenes to produce unprecedented millimetric polyethylene beads without loss of catalytic activity.Read less <
English Keywords
STAR-LIKE POLYSTYRENES
ETHYLENE POLYMERIZATION
OLEFIN POLYMERIZATION
CATALYTIC-SYSTEM
SUPPORTS
Origin
Hal imported