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Hybrid PEDOT-Metal Nanoparticles - New Substitutes for PEDOT:PSS in Electrochromic Layers - Towards Improved Performance

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorMUMTAZ, Muhammad
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorOUVRARD, Blanche
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMAILLAUD, Laurent
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLABRUGÈRE, Christine
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCRAMAIL, Henri
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDELVILLE, Marie-Hélène
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2012
dc.identifier.issn1434-1948
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20456
dc.description.abstractEnHybrid organicinorganic nanocomposites of poly(3,4-ethylenedioxythiophene) (PEDOT) and silver or gold {PEDOTmetal (PEDOTM) nano-objects (M = Ag, Au) (particle diameter down to 60 nm)} were prepared by a one-pot oxidative aqueous dispersion polymerization using ammonium persulfate as an oxidant and the corresponding metal salts as co-oxidant (HAuCl4 and AgNO3) in the presence of pyrrole-modified-poly(N-vinylpyrrolidone-co-vinyl alcohol) (PVP-co-PVAL-mod-Py) stabilizer. The hydrophilic character of such a stabilizer enhances the polymer layer through hydrophilic interactions, which leads to a smooth surface with high wetting properties for subsequent electropolymerizations. PEDOTM is more conducting than the commercially available PEDOT:PSS, in which the PSS acts as an insulating agent (electrical conductivities up to 1.25 Scm(-1)). These nanocomposites were used to replace PEDOT:PSS as anchoring layer for further EDOT monomer polymerization, providing an improvement of the electrochromic properties of PEDOT in terms of not only contrast ratio and coloration efficiency but also switching time response
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.enOxidation
dc.subject.enPolymerization
dc.subject.enOrganic-inorganic hybrid composites
dc.subject.enNano-particles
dc.subject.enElectrochromism
dc.title.enHybrid PEDOT-Metal Nanoparticles - New Substitutes for PEDOT:PSS in Electrochromic Layers - Towards Improved Performance
dc.typeArticle de revue
dc.identifier.doi10.1002/ejic.201200856
dc.subject.halChimie/Polymères
bordeaux.journalEuropean Journal of Inorganic Chemistry
bordeaux.page5360-5370
bordeaux.volume32
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issueSI
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00803498
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00803498v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=European%20Journal%20of%20Inorganic%20Chemistry&rft.date=2012&rft.volume=32&rft.issue=SI&rft.spage=5360-5370&rft.epage=5360-5370&rft.eissn=1434-1948&rft.issn=1434-1948&rft.au=MUMTAZ,%20Muhammad&OUVRARD,%20Blanche&MAILLAUD,%20Laurent&LABRUG%C3%88RE,%20Christine&CLOUTET,%20Eric&rft.genre=article


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