Rapid and controlled synthesis of hydrophobic polyethers by monomer activation
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | GERVAIS, Matthieu | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | BROCAS, Anne-Laure | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | DEFFIEUX, Alain | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | IBARBOURE, Emmanuel | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | CARLOTTI, Stéphane | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2012 | |
| dc.identifier.issn | 0033-4545 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20442 | |
| dc.description.abstractEn | A series of polyethers was prepared by monomer-activated anionic polymerization. The combination of an ammonium salt with triisobutylaluminum allowed the polymerization of epoxides containing various aliphatic side chains (1,2-butene oxide (BO), 1,2-hexene oxide (HO), and 1,2-octadecene oxide (ODO)) or a fluorinated group (3,3,3-trifluoro-1,2-epoxypropane (TFEP)). Polymers of molar masses up to 35 000 g/mol with relatively narrow molar mass distribution could be synthesized. Polymer structures were analyzed by C-13 NMR, and the thermal behavior was studied by differential scanning calorimetry (DSC). The evolution of hydrophobicity was investigated according to the length and composition of the side chain. Using a long aliphatic side-chain epoxide (C16) imparted crystallinity to the resulting atactic polymer. | |
| dc.language.iso | en | |
| dc.publisher | De Gruyter | |
| dc.subject.en | polymerization | |
| dc.subject.en | ring-opening | |
| dc.subject.en | hydrophobicity | |
| dc.subject.en | monomer activation | |
| dc.subject.en | polyether | |
| dc.subject.en | poly(alkylene oxide) | |
| dc.title.en | Rapid and controlled synthesis of hydrophobic polyethers by monomer activation | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1351/PAC-CON-11-11-1616 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Pure and Applied Chemistry | |
| bordeaux.page | 2103-2111 | |
| bordeaux.volume | 84 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 10 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00817190 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00817190v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Pure%20and%20Applied%20Chemistry&rft.date=2012&rft.volume=84&rft.issue=10&rft.spage=2103-2111&rft.epage=2103-2111&rft.eissn=0033-4545&rft.issn=0033-4545&rft.au=GERVAIS,%20Matthieu&BROCAS,%20Anne-Laure&DEFFIEUX,%20Alain&IBARBOURE,%20Emmanuel&CARLOTTI,%20St%C3%A9phane&rft.genre=article |
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