Afficher la notice abrégée

Aliphatic polycarbonates and poly(ester carbonate)s from fatty acid derived monomers

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorMORE, Arvind S.
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorPALASKAR, Dnyaneshwar V
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierInstitut des Corps Gras [ITERG]
dc.contributor.authorGADENNE, Benoît
hal.structure.identifierInstitut des Corps Gras [ITERG]
dc.contributor.authorALFOS, Carine
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCRAMAIL, Henri
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2011
dc.identifier.issn1759-9954
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20422
dc.description.abstractEnFatty acid derivatives were efficiently used as starting materials for the synthesis of polycarbonates and poly(ester carbonate)s. A novel AB-type self-condensable monomer, ethyl(9-hydroxy-10-methoxyoctadecyl)carbonate (EHMOC) and a dicarbonate monomer, 4-[(ethoxycarbonyl)oxy]butyl-12-[(ethoxycarbonyl)oxy]octadec-9-enoate (EOBEOE) were prepared from oleyl alcohol and ricinoleic acid, respectively. Of these, EHMOC was polymerized by the alcohol-carbonate exchange self-polycondensation approach, while EOBEOE was polycondensed with various biobased diols to give polycarbonates and poly(ester carbonate) s, respectively. The monomers and polymers were well characterized by FTIR and H-1-NMR spectroscopy. The C-13-NMR spectroscopy revealed the formation of randomly distributed sequences in the poly(ester carbonate) s due to the carbonate interchange reaction. An unexpected formation of polyricinoleate was observed and confirmed by NMR and MALDI-TOF spectroscopy. Most of the polymers displayed good thermal stability with the temperature at 10% weight loss in the range 273-325 degrees C. Due to the presence of aliphatic segments, these materials exhibit very low glass transition temperature.
dc.language.isoen
dc.publisherRoyal Society of Chemistry - RSC
dc.subject.enPOLYURETHANES
dc.subject.enOIL
dc.subject.enDIOLS
dc.subject.enDIOXIDE
dc.subject.enPOLYMERS
dc.subject.enRING-OPENING POLYMERIZATION
dc.subject.enRENEWABLE RESOURCES
dc.subject.enALTERNATING COPOLYMERIZATION
dc.subject.enCYCLIC CARBONATES
dc.subject.enPOLYESTERS
dc.title.enAliphatic polycarbonates and poly(ester carbonate)s from fatty acid derived monomers
dc.typeArticle de revue
dc.identifier.doi10.1039/c1py00326g
dc.subject.halChimie/Polymères
bordeaux.journalPolymer Chemistry
bordeaux.page2796-2803
bordeaux.volume2
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue12
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00818377
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00818377v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polymer%20Chemistry&rft.date=2011&rft.volume=2&rft.issue=12&rft.spage=2796-2803&rft.epage=2796-2803&rft.eissn=1759-9954&rft.issn=1759-9954&rft.au=MORE,%20Arvind%20S.&PALASKAR,%20Dnyaneshwar%20V&CLOUTET,%20Eric&GADENNE,%20Beno%C3%AEt&ALFOS,%20Carine&rft.genre=article


Fichier(s) constituant ce document

FichiersTailleFormatVue

Il n'y a pas de fichiers associés à ce document.

Ce document figure dans la(les) collection(s) suivante(s)

Afficher la notice abrégée