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Vegetable-based building-blocks for the synthesis of thermoplastic renewable polyurethanes and polyesters

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorMORE, Arvind S.
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorMAISONNEUVE, Lise
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorLEBARBÉ, Thomas
hal.structure.identifierInstitut des Corps Gras [ITERG]
dc.contributor.authorGADENNE, Benoît
hal.structure.identifierInstitut des Corps Gras [ITERG]
dc.contributor.authorALFOS, Carine
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCRAMAIL, Henri
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2013
dc.identifier.issn1438-7697
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20418
dc.description.abstractEnFatty acid derivatives, viz, methyl oleate and methyl 10-undecenoate were systematically explored to obtain a set of monomers with defined functionality. More specifically, AB-type self-condensable monomers containing hydroxyl-acyl azide functionality and diols with pre-formed ester linkage were synthesized. A series of polyurethanes was prepared using two methods: (i) AB-type self-polycondensation reaction of hydroxyl-acyl azide moiety, and (ii) polymerization of diols with isophorone diisocyanate and methylene diphenyl diisocyanate. The diols were also reacted with a bio-sourced diester using organocatalyst to obtain a set of polyesters. The obtained polyurethanes and polyesters were thoroughly analyzed with fourier-transformed infrared, nuclear magnetic resonance, size exclusion chromatography, differential scanning calorimetry and thermogravimetric analysis experiments. The polymers displayed amorphous to semi-crystalline behaviors with regard to the structure of the monomers. Both, polyurethanes and polyesters displayed a good thermal stability with no significant weight loss below 200 degrees C.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.enThermoplastic polyesters
dc.subject.enThermoplastic polyurethanes
dc.subject.enMethyl undecenoate
dc.subject.enMethyl oleate
dc.subject.enVegetable oils
dc.title.enVegetable-based building-blocks for the synthesis of thermoplastic renewable polyurethanes and polyesters
dc.typeArticle de revue
dc.identifier.doi10.1002/ejlt.201200172
dc.subject.halChimie/Polymères
bordeaux.journalEuropean Journal of Lipid Science and Technology
bordeaux.page61-75
bordeaux.volume115
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue1, SI
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00818424
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00818424v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=European%20Journal%20of%20Lipid%20Science%20and%20Technology&rft.date=2013&rft.volume=115&rft.issue=1,%20SI&rft.spage=61-75&rft.epage=61-75&rft.eissn=1438-7697&rft.issn=1438-7697&rft.au=MORE,%20Arvind%20S.&MAISONNEUVE,%20Lise&LEBARB%C3%89,%20Thomas&GADENNE,%20Beno%C3%AEt&ALFOS,%20Carine&rft.genre=article


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