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N-Acetoxy-phthalimide (NAPI) as a new H-abstracting agent at high temperature: application to the melt functionalization of polyethylene

dc.rights.licenseopen
hal.structure.identifierIngénierie des Matériaux Polymères [IMP]
dc.contributor.authorBELEKIAN, Denis
hal.structure.identifierIngénierie des Matériaux Polymères [IMP]
dc.contributor.authorCASSAGNAU, Philippe
hal.structure.identifierCentre de recherche, développement, applications et technique de l'ouest [CERDATO]
dc.contributor.authorFLAT, Jean-Jacques
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorQUINEBÈCHE, Sébastien
dc.contributor.authorAUTISSIER, Laurent
hal.structure.identifierInstitut de Chimie Radicalaire [ICR]
dc.contributor.authorBERTIN, Denis
dc.contributor.authorSIRI, Didier
hal.structure.identifierInstitut de Chimie Radicalaire [ICR]
dc.contributor.authorGIGMES, Didier
hal.structure.identifierInstitut de Chimie Radicalaire [ICR]
dc.contributor.authorGUILLANEUF, Yohann
hal.structure.identifierIngénierie des Matériaux Polymères [IMP]
dc.contributor.authorCHAUMONT, Philippe
hal.structure.identifierIngénierie des Matériaux Polymères [IMP]
dc.contributor.authorBEYOU, Emmanuel
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2013
dc.identifier.issn1759-9954
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20408
dc.description.abstractEnA new H-abstracting agent, N-acetoxy-phthalimide (NAPI), was designed that cleaves mainly homolytically into acyloxyl and aminyl radicals at 190 degrees C. Melt PE grafting experiments confirmed the H-abstraction efficiency of NAPI. It was also shown that the grafting of maleic anhydride increased and at the same time undesired crosslinking lowered compared to peroxides.
dc.language.isoen
dc.publisherRoyal Society of Chemistry - RSC
dc.subject.enBOND-DISSOCIATION ENERGIES
dc.subject.enMALEIC-ANHYDRIDE
dc.subject.enRADICALS
dc.subject.enPOLYMERIZATION
dc.subject.enSELECTIVITY
dc.subject.enACID
dc.title.enN-Acetoxy-phthalimide (NAPI) as a new H-abstracting agent at high temperature: application to the melt functionalization of polyethylene
dc.typeArticle de revue
dc.identifier.doi10.1039/c3py00246b
dc.subject.halChimie/Polymères
dc.subject.halChimie/Matériaux
bordeaux.journalPolymer Chemistry
bordeaux.page2676-2679
bordeaux.volume4
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00870517
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00870517v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polymer%20Chemistry&rft.date=2013&rft.volume=4&rft.spage=2676-2679&rft.epage=2676-2679&rft.eissn=1759-9954&rft.issn=1759-9954&rft.au=BELEKIAN,%20Denis&CASSAGNAU,%20Philippe&FLAT,%20Jean-Jacques&QUINEB%C3%88CHE,%20S%C3%A9bastien&AUTISSIER,%20Laurent&rft.genre=article


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