Phenols and Tertiary Amines: An Amazingly Simple Hydrogen-Bonding Organocatalytic System Promoting Ring Opening Polymerization
THOMAS, Coralie
Institut des Sciences Moléculaires [ISM]
Laboratoire de Chimie des Polymères Organiques [LCPO]
Institut des Sciences Moléculaires [ISM]
Laboratoire de Chimie des Polymères Organiques [LCPO]
PERUCH, Frédéric
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
DEFFIEUX, Alain
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Leer más >
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
THOMAS, Coralie
Institut des Sciences Moléculaires [ISM]
Laboratoire de Chimie des Polymères Organiques [LCPO]
Institut des Sciences Moléculaires [ISM]
Laboratoire de Chimie des Polymères Organiques [LCPO]
PERUCH, Frédéric
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
DEFFIEUX, Alain
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
< Leer menos
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Idioma
en
Article de revue
Este ítem está publicado en
Advanced Synthesis and Catalysis. 2011, vol. 353, n° 7, p. 1049-1054
Wiley-VCH Verlag
Resumen en inglés
A simple and easily available organocatalytic system was developed for the polymerization of lactide. In partnership with tertiary amines, phenol derivatives were demonstrated to be excellent single H-bonding catalysts ...Leer más >
A simple and easily available organocatalytic system was developed for the polymerization of lactide. In partnership with tertiary amines, phenol derivatives were demonstrated to be excellent single H-bonding catalysts with high conversion within 24 h. In particular, ortho-, meta- and meta,meta'-trifluoromethylphenols revealed an amazing capacity for triggering the controlled ring opening polymerization (ROP) of lactide, through a fitted hydrogen-bond with the monomer.< Leer menos
Palabras clave en inglés
phenols
polymerization
polylactide
hydrogen bonds
organic catalysis
Orígen
Importado de HalCentros de investigación