Microcellular foaming of amorphous polymers in a supercritical CO2 batch process: Effect of philic-additives and process conditions on microstructure
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | REGLERO RUIZ, José Antonio | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | DUMON, Michel | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2010 | |
| dc.identifier.issn | 1790-4439 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20357 | |
| dc.description.abstractEn | Microcellular foaming of commodity amorphous polymers, Polymethylmethacrylate (PMMA), and Polystyrene (PS) was studied in supercritical CO 2 via a one-step process in the presence of several types of additives able to change their foaming behaviour and therefore the porous structures. Additives such as diblock copolymers (styrene-co-methylmethacrylate SM) or triblock (styrene-co-butadiene-co-methylmethacrylate SBM, methylmethacrylate-co-butylacrylate-co-methylmethacrylate MAM) terpolymers, core-shell particles (methylmethacrylate styrene) were added to PS or PMMA by extrusion. They showed advantages compared to classical PS-PMMA polymer blends in terms of cell size control and reduction of cell size. Foaming is carried out on bulk injection molded samples which were saturated under high pressures of CO 2 (300 bars) at different temperatures (25°C to 80°C) and different depressurization rates (from 150bar/min to 12bar/min). Then very distinct cellular structures and densities were controlled by varying either the additive type or the foaming conditions, using different foaming temperatures and foaming times. Cell sizes are ranging from 0.2 μm to 200 μm, and densities from 0.30 g/cm3 to 1 g/cm 3 in the polymers considered. It was found that the some additives, well dispersed inside the polymer matrix, play an important role as nucleating agents, reducing drastically the average cell size, and improving the foaming process. | |
| dc.language.iso | en | |
| dc.publisher | ADCOTEC | |
| dc.subject.en | Amorphous polymers | |
| dc.subject.en | Batch process | |
| dc.subject.en | Cell size | |
| dc.subject.en | Cellular structure | |
| dc.subject.en | Core-shell particle | |
| dc.subject.en | Depressurization rate | |
| dc.subject.en | Foaming process | |
| dc.subject.en | Foaming temperature | |
| dc.subject.en | High pressure | |
| dc.subject.en | Methyl methacrylates | |
| dc.subject.en | Microcellular foaming | |
| dc.subject.en | Nucleating agents | |
| dc.subject.en | One-step process | |
| dc.subject.en | Porous structures | |
| dc.subject.en | Process condition | |
| dc.subject.en | Supercritical CO | |
| dc.subject.en | Supercritical CO2 | |
| dc.subject.en | Triblocks | |
| dc.subject.en | Well-dispersed | |
| dc.title.en | Microcellular foaming of amorphous polymers in a supercritical CO2 batch process: Effect of philic-additives and process conditions on microstructure | |
| dc.type | Article de revue | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Journal of Nanostructured Polymers and Nanocomposites | |
| bordeaux.page | 54-60 | |
| bordeaux.volume | 6 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 2 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00950601 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00950601v1 | |
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