Xanthates as chain-transfer agents in controlled radical polymerization (MADIX): Structural effect of the O-alkyl group
| dc.rights.license | open | |
| hal.structure.identifier | Rhodia Recherches | |
| dc.contributor.author | DESTARAC, M. | |
| hal.structure.identifier | Rhodia Recherches | |
| dc.contributor.author | BZDUCHA, W. | |
| hal.structure.identifier | Rhodia Recherches | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | TATON, Daniel | |
| hal.structure.identifier | Laboratoire de synthèse organique [DCSO] | |
| dc.contributor.author | GAUTHIER-GILLAIZEAU, Isabelle | |
| hal.structure.identifier | Laboratoire de synthèse organique [DCSO] | |
| dc.contributor.author | ZARD, Samir | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2002 | |
| dc.identifier.issn | 1022-1336 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20345 | |
| dc.description.abstractEn | The capability of three chain-transfer agents, O-alkyl-S-(1-ethoxycarbonyl)ethyl xanthates (CH3-CHCO2C2H5)S(C=S)OZ', to control the free-radical polymerization of styrene and ethyl acrylate by the MADIX process was examined. The reactivity of the xanthates varied according to the following trend: Z' = CH2CH3 < CH2CF3 < CH[P(O)(OEt)2]CF3. This change in reactivity allowed a lowering of the polydispersity index from 2.0 for Z' = CH2CH3 to 1.15 for Z' = CH[P(O)(OEt)2]CF3 in the case of the polymerization of styrene. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.title.en | Xanthates as chain-transfer agents in controlled radical polymerization (MADIX): Structural effect of the O-alkyl group | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/marc.200290002 | |
| bordeaux.journal | Macromolecular Rapid Communications | |
| bordeaux.page | 1049-1054 | |
| bordeaux.volume | 23 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 17 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00954865 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00954865v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Rapid%20Communications&rft.date=2002&rft.volume=23&rft.issue=17&rft.spage=1049-1054&rft.epage=1049-1054&rft.eissn=1022-1336&rft.issn=1022-1336&rft.au=DESTARAC,%20M.&BZDUCHA,%20W.&TATON,%20Daniel&GAUTHIER-GILLAIZEAU,%20Isabelle&ZARD,%20Samir&rft.genre=article |
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