A Catalyst Platform for Unique Cationic (Co)Polymerization in Aqueous Emulsion
| dc.rights.license | open | |
| hal.structure.identifier | Research Institute for Physical Chemical Problems of the Belarusian State University | |
| dc.contributor.author | V. VASILENKO, Irina | |
| dc.contributor.author | YEONG, Hui Yee | |
| hal.structure.identifier | Ingénierie des Matériaux Polymères [IMP] | |
| dc.contributor.author | DELGADO, Marco | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | OUARDAD, Samira | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | PERUCH, Frédéric
IDREF: 152900748 | |
| dc.contributor.author | VOIT, Brigitte | |
| hal.structure.identifier | Ingénierie des Matériaux Polymères [IMP] | |
| dc.contributor.author | GANACHAUD, Francois | |
| dc.contributor.author | KOSTJUK, Sergei V. | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2015 | |
| dc.identifier.issn | 1433-7851 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20290 | |
| dc.description.abstractEn | Sodium dodecyl benzene sulfonate (DBSNa) surfactants, with a polydisperse and hyperbranched structure, combined with different rare earth metal salts generate highly water-dispersible Lewis acid surfactant combined catalysts (LASCs). This platform of new complexes promotes fast, efficient cationic polymerization of industrially relevant monomers in direct emulsion at moderate temperature. The process described here does not require high shearing, long polymerization time, or large catalyst content. It allows the reproducible generation of high-molar-mass homopolymers of pMOS, styrene, and isoprene, as well as random or multiblock copolymers of the latter two, in a simple and straightforward one-pot reaction. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | styrene | |
| dc.subject.en | polymerization | |
| dc.subject.en | Lewis acids | |
| dc.subject.en | isoprene | |
| dc.subject.en | heterogeneous catalysis | |
| dc.title.en | A Catalyst Platform for Unique Cationic (Co)Polymerization in Aqueous Emulsion | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/anie.201501157 | |
| dc.subject.hal | Chimie/Polymères | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Angewandte Chemie International Edition | |
| bordeaux.page | 12728-12732 | |
| bordeaux.volume | 54 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01231691 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01231691v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.date=2015&rft.volume=54&rft.spage=12728-12732&rft.epage=12728-12732&rft.eissn=1433-7851&rft.issn=1433-7851&rft.au=V.%20VASILENKO,%20Irina&YEONG,%20Hui%20Yee&DELGADO,%20Marco&OUARDAD,%20Samira&PERUCH,%20Fr%C3%A9d%C3%A9ric&rft.genre=article |
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